Carbon pentoxide

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Carbon pentoxide
Carbon-pentoxide-2D.png
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Names
IUPAC name
tetraoxolan-5-one
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/CO5/c2-1-3-5-6-4-1
    Key: CTQBRSUCLFHKGM-UHFFFAOYSA-N
  • O=C1OOOO1
Properties
CO5
Molar mass 92.01 g/mol
Related compounds
Related compounds
Carbon hexoxide
Carbon tetroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Carbon pentaoxide or carbon pentoxide is an unstable molecular oxide of carbon. The molecule has been produced and studied at cryogenic temperatures. The molecule is important in atmospheric chemistry and in the study of cold ices in the outer solar system and interstellar space. [1] The substance could form and be present on Ganymede or Triton, moons in the outer solar system.

Contents

The molecule has a C2 symmetry. It consists of a five membered ring with one carbon and four oxygen atoms. A fifth oxygen atom has a double bond to the carbon. Calculation has resulted in a theoretical structure. The pentagon is not regular, but varies in the length of its sides and angles. The distance between the oxygen atoms that are not attached to carbon is 1.406 Å, whereas the distance between one of these atoms and an oxygen attached to carbon is 1.457 Å. The carbon oxygen bond length is 1.376 Å. The double carbon to oxygen bond is the shortest at 1.180 Å. There is no carbon-to-carbon bond as there is only one carbon atom. The OOO bond angle is 100.2° and the OOC angle is 109.1°. The OCO bond angle is 125.4°. [2]

Production

Carbon pentaoxide was produced by irradiating cryogenically frozen carbon dioxide with 5 keV electrons. The reaction mechanism is by carbon tetroxide reacting with an oxygen atom. This reaction releases 17.0 kJmol−1. [2] Formation from ozone and carbon dioxide is energetically unfavourable by 165.6 kJmol−1, and carbon trioxide reacting with dioxygen molecules also would require 31.6 kJmol−1. [3]

Properties

Vibrational infrared wavenumbers include the most prominent ν1 1912 cm−1 for the most common isotopologue 12C16O5. [2] Potential routes for decomposition are by forming carbon dioxide and ozone, or carbon monoxide and oxygen, or carbon trioxide and oxygen. [3] Carbon pentaoxide is less volatile than carbon dioxide, remaining stable and solid until about 106K. [2]

An alternative theoretical structure, termed C2v, has a spiro structure with one four-member ring and a three-member ring tied perpendicularly at the carbon atom. However, this is 166 kJmol−1 higher in energy than the C2 isomer, and thus less likely to be formed. This isomer has not been detected. [1]

The equivalent carbon pentasulfide is also known from inert gas matrix. It has C2 symmetry with the same atomic topology as the pentoxide. [4]

Related Research Articles

Molecule Electrically neutral group of two or more atoms

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.

Sulfur trioxide (alternative spelling sulphur trioxide, also known as nisso sulfan) is the chemical compound with the formula SO3. It has been described as "unquestionably the most important economically" sulfur oxide. It is prepared on an industrial scale as a precursor to sulfuric acid.

Dinitrogen pentoxide Chemical compound

Dinitrogen pentoxide is the chemical compound with the formula N
2
O
5
, also known as nitrogen pentoxide or nitric anhydride. It is one of the binary nitrogen oxides, a family of compounds that only contain nitrogen and oxygen. It exists as colourless crystals that melt at 41 °C. Its boiling point is 47 °C, and sublimes slightly above room temperature, yielding a colorless gas.

Uranium trioxide Chemical compound

Uranium trioxide (UO3), also called uranyl oxide, uranium(VI) oxide, and uranic oxide, is the hexavalent oxide of uranium. The solid may be obtained by heating uranyl nitrate to 400 °C. Its most commonly encountered polymorph, γ-UO3, is a yellow-orange powder.

Carbon trioxide Chemical compound

Carbon trioxide (CO3) is an unstable oxide of carbon (an oxocarbon). The possible isomers of carbon trioxide include ones with molecular symmetry point groups Cs, D3h, and C2v. The C2v state, consisting of a dioxirane has been shown to be the ground state of the molecule. Carbon trioxide should not be confused with the stable carbonate ion (CO32−).

Dithiete Chemical compound

Dithiete is an unsaturated heterocyclic compound that contains two adjacent sulfur atoms and two sp2-hybridized carbon centers. Derivatives are known collectively as dithietes or 1,2-dithietes. With 6 π electrons, 1,2-dithietes are examples of aromatic organosulfur compounds. A few 1,2-dithietes have been isolated.

Dioxirane Chemical compound

In chemistry, dioxirane is a compound with formula CH
2
O
2
, whose molecule consists of a ring with one carbon and two oxygen atoms, and two hydrogen atoms attached to the carbon. It is a heterocyclic compound, the smallest cyclic organic peroxide.

Oxocarbon

An oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen. The simplest and most common oxocarbons are carbon monoxide (CO) and carbon dioxide (CO2). Many other stable (practically if not thermodynamically) or metastable oxides of carbon are known, but they are rarely encountered, such as carbon suboxide (C3O2 or O=C=C=C=O) and mellitic anhydride (C12O9).

Nitrate radical Chemical compound

Trioxidonitrogen(•) or nitrate radical is an oxide of nitrogen with formula NO
3
, consisting of three oxygen atoms covalently bound to a nitrogen atom. This highly unstable blue compound has not been isolated in pure form, but can be generated and observed as a short-lived component of gas, liquid, or solid systems.

Carbon tetroxide Chemical compound

Carbon tetroxide is a highly unstable oxide of carbon with formula CO
4
. It was proposed as an intermediate in the O-atom exchange between carbon dioxide and oxygen at high temperatures. The C2v isomer, which is -138 kJ mol−1 more stable than the D2d isomer, was first detected in electron-irradiated ices of carbon dioxide via infrared spectroscopy.

Oxocarbon anion

In chemistry, an oxocarbon anion is a negative ion consisting solely of carbon and oxygen atoms, and therefore having the general formula C
x
On
y
for some integers x, y, and n.

Disulfur dioxide Chemical compound

Disulfur dioxide, dimeric sulfur monoxide or SO dimer is an oxide of sulfur with the formula S2O2. The solid is unstable with a lifetime of a few seconds at room temperature.

Carbon hexoxide Chemical compound

Carbon hexoxide or carbon hexaoxide is an oxide of carbon with an unusually large quantity of oxygen. The molecule has been produced and studied at cryogenic temperatures. The molecule is important in atmospheric chemistry and in the study of cold ices in the outer solar system and interstellar space. The substance could form and be present on Ganymede or Triton, moons in the outer solar system. The molecule consists of a six membered ring with five oxygen and one carbon atom, and one oxygen with a double bond with the carbon.

Chlorine peroxide Chemical compound

Chlorine peroxide is a molecular compound with formula ClOOCl. Chemically, it is a dimer of the chlorine monoxide radical (ClO·). It is important in the formation of the ozone hole. Chlorine peroxide catalytically converts ozone into oxygen when it is irradiated by ultraviolet light.

Neon compounds are chemical compounds containing the element neon (Ne) with other molecules or elements from the periodic table. Compounds of the noble gas neon were believed not to exist, but there are now known to be molecular ions containing neon, as well as temporary excited neon-containing molecules called excimers. Several neutral neon molecules have also been predicted to be stable, but are yet to be discovered in nature. Neon has been shown to crystallize with other substances and form clathrates or Van der Waals solids.

Argon compounds, the chemical compounds that contain the element argon, are rarely encountered due to the inertness of the argon atom. However, compounds of argon have been detected in inert gas matrix isolation, cold gases, and plasmas, and molecular ions containing argon have been made and also detected in space. One solid interstitial compound of argon, Ar1C60 is stable at room temperature. Ar1C60 was discovered by the CSIRO.

Tricarbon monoxide Chemical compound

Tricarbon monoxide C3O is a reactive radical oxocarbon molecule found in space, and which can be made as a transient substance in the laboratory. It can be trapped in an inert gas matrix or made as a short lived gas. C3O can be classified as a ketene or an oxocumulene a kind of heterocumulene.

A heterocumulene is a molecule or ion containing a chain of at least three double bonds between consecutive atoms, in which one or more atoms in the doubly bonded chain is a heteroatom. Such species are analogous to a cumulene in which the chain of doubly bonded atoms contains only carbon, except that at least one carbon is replaced by a heteroatom. Some authors relax the definition to include species with chains of only two double bonds between consecutive atoms, also known as heteroallenes.

Sulfoxylic acid Chemical compound

Sulfoxylic acid (H2SO2) (also known as hyposulfurous acid or sulfur dihydroxide) is an unstable oxoacid of sulfur in an intermediate oxidation state between hydrogen sulfide and dithionous acid. It consists of two hydroxy groups attached to a sulfur atom. Sulfoxylic acid contains sulfur in an oxidation state of +2. Sulfur monoxide (SO) can be considered as a theoretical anhydride for sulfoxylic acid, but it is not actually known to react with water.

Phosphorus monoxide Chemical compound

Phosphorus monoxide is an unstable radical inorganic compound with molecular formula PO.

References

  1. 1 2 Kaiser, Ralf I.; Alexander M. Mebel (2008). "On the formation of higher carbon oxides in extreme environments". Chemical Physics Letters. 465 (1–3): 1–9. Bibcode:2008CPL...465....1K. doi:10.1016/j.cplett.2008.07.076. ISSN   0009-2614.
  2. 1 2 3 4 Jamieson, Corey S.; Alexander M. Mebel; Ralf I. Kaiser (2007). "First detection of the C2 symmetric isomer of carbon pentaoxide (CO5) at 10K". Chemical Physics Letters. 443 (1–3): 49–54. Bibcode:2007CPL...443...49J. doi:10.1016/j.cplett.2007.06.009. ISSN   0009-2614.
  3. 1 2 Elliott, Ben M.; Alexander I. Boldyrev (2005). "The Oxygen-Rich Carboxide Series: COn(n= 3, 4, 5, 6, 7, or 8)". The Journal of Physical Chemistry A. 109 (16): 3722–3727. Bibcode:2005JPCA..109.3722E. doi:10.1021/jp0449455. ISSN   1089-5639. PMID   16839040.
  4. Maity, Surajit; Kim, Y.S.; Kaiser, Ralf I.; Lin, Hong Mao; Sun, Bian Jian; Chang, A.H.H. (July 2013). "On the detection of higher order carbon sulfides (CSx; x=4–6) in low temperature carbon disulfide ices". Chemical Physics Letters. 577: 42–47. Bibcode:2013CPL...577...42M. doi:10.1016/j.cplett.2013.05.039.