Europium(II) sulfide

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Europium(II) sulfide
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Names
IUPAC name
europium(II) sulfide
Identifiers
3D model (JSmol)
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PubChem CID
  • [Eu+2].[S-2]
Properties
EuS
Molar mass 184.03 g/mol
Appearanceblack powder
Melting point 2,250 °C (4,080 °F; 2,520 K)
+25,730;·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Europium(II) sulfide is the inorganic compound with the chemical formula EuS. It is a black, air-stable powder. Europium possesses an oxidation state of +II in europium sulfide, whereas the lanthanides exhibit a typical oxidation state of +III. [1] Its Curie temperature (Tc) is 16.6 K. Below this temperature EuS behaves like a ferromagnetic compound, and above it exhibits simple paramagnetic properties. [2] EuS is stable up to 500 °C in air, when it begins to show signs of oxidation. In an inert environment it decomposes at 1470 °C. [3]

Contents

Structure

EuS crystallizes in face-centered cubic (FCC) crystal lattice with the rock salt structure. Both europium and sulfur have octahedral coordination geometry with a coordination number of six. [4] [5] The Eu-S bond lengths are 2.41 Å.

Preparation

In the preparation of EuS, powdered europium(III) oxide (Eu2O3) is treated with hydrogen sulfide (H2S) at 1150 °C. The crude EuS product is purified by heating at 900 °C under vacuum to remove excess sulfur. [4] [3]

Eu2O3 + 3 H2S → 2 EuS + 3 H2O + S

EuS has additionally been synthesized from europium dichloride (EuCl2), however, such products tend to be contaminated by chloride. [4]

Research

In the past few decades, a new interest has been exhibited in the synthesis of EuS, as well as its oxygen analog EuO, because of their potential as laser window materials, insulating ferromagnets, ferromagnetic semiconductors, and magnetoresistant, optomagnetic, and luminescent materials. [3] [2] EuS was used in an experiment providing evidence of Majorana fermions relevant to quantum computing and the production of qubits. [6]

Related Research Articles

<span class="mw-page-title-main">Europium</span> Chemical element, symbol Eu and atomic number 63

Europium is a chemical element; it has symbol Eu and atomic number 63. Europium is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. It is the most chemically reactive, least dense, and softest of the lanthanide elements. It is soft enough to be cut with a knife. Europium was isolated in 1901 and named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.

Sulfide (also sulphide in British English ) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. Sulfide also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (SH) are the conjugate acids of sulfide.

<span class="mw-page-title-main">Zinc sulfide</span> Inorganic compound

Zinc sulfide is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment. In its dense synthetic form, zinc sulfide can be transparent, and it is used as a window for visible optics and infrared optics.

<span class="mw-page-title-main">Lead(II) sulfide</span> Chemical compound

Lead(II) sulfide is an inorganic compound with the formula PbS. Galena is the principal ore and the most important compound of lead. It is a semiconducting material with niche uses.

<span class="mw-page-title-main">Europium(III) chloride</span> Chemical compound

Europium(III) chloride is an inorganic compound with the formula EuCl3. The anhydrous compound is a yellow solid. Being hygroscopic it rapidly absorbs water to form a white crystalline hexahydrate, EuCl3·6H2O, which is colourless. The compound is used in research.

<span class="mw-page-title-main">Sodium hydrosulfide</span> Chemical compound

Sodium hydrosulfide is the chemical compound with the formula NaSH. This compound is the product of the half-neutralization of hydrogen sulfide with sodium hydroxide (NaOH). NaSH and sodium sulfide are used industrially, often for similar purposes. Solid NaSH is colorless. The solid has an odor of H2S owing to hydrolysis by atmospheric moisture. In contrast with sodium sulfide, which is insoluble in organic solvents, NaSH, being a 1:1 electrolyte, is more soluble.

<span class="mw-page-title-main">Tungsten disulfide</span> Chemical compound

Tungsten disulfide is an inorganic chemical compound composed of tungsten and sulfur with the chemical formula WS2. This compound is part of the group of materials called the transition metal dichalcogenides. It occurs naturally as the rare mineral tungstenite. This material is a component of certain catalysts used for hydrodesulfurization and hydrodenitrification.

<span class="mw-page-title-main">Silicon disulfide</span> Chemical compound

Silicon disulfide is the inorganic compound with the formula SiS2. Like silicon dioxide, this material is polymeric, but it adopts a 1-dimensional structure quite different from the usual forms of SiO2.

<span class="mw-page-title-main">Selenium compounds</span> Chemical compounds containing selenium

Selenium compounds are compounds containing the element selenium (Se). Among these compounds, selenium has various oxidation states, the most common ones being −2, +4, and +6. Selenium compounds exist in nature in the form of various minerals, such as clausthalite, guanajuatite, tiemannite, crookesite etc., and can also coexist with sulfide minerals such as pyrite and chalcopyrite. For many mammals, selenium compounds are essential. For example, selenomethionine and selenocysteine are selenium-containing amino acids present in the human body. Selenomethionine participates in the synthesis of selenoproteins. The reduction potential and pKa (5.47) of selenocysteine are lower than those of cysteine, making some proteins have antioxidant activity. Selenium compounds have important applications in semiconductors, glass and ceramic industries, medicine, metallurgy and other fields.

Thiosulfuric acid is the inorganic compound with the formula H2S2O3. It has attracted academic interest as a simple, easily accessed compound that is labile. It has few practical uses.

<span class="mw-page-title-main">Copper(I) sulfide</span> Chemical compound

Copper(I) sulfide is a copper sulfide, a chemical compound of copper and sulfur. It has the chemical compound Cu2S. It is found in nature as the mineral chalcocite. It has a narrow range of stoichiometry ranging from Cu1.997S to Cu2.000S. Samples are typically black.

<span class="mw-page-title-main">Gold(I) sulfide</span> Chemical compound

Gold(I) sulfide is the inorganic compound with the formula Au2S. It is the principal sulfide of gold. It decomposes to gold metal and elemental sulfur, illustrating the "nobility" of gold.

<span class="mw-page-title-main">Titanium disulfide</span> Inorganic chemical compound

Titanium disulfide is an inorganic compound with the formula TiS2. A golden yellow solid with high electrical conductivity, it belongs to a group of compounds called transition metal dichalcogenides, which consist of the stoichiometry ME2. TiS2 has been employed as a cathode material in rechargeable batteries.

<span class="mw-page-title-main">Disulfur dioxide</span> Chemical compound

Disulfur dioxide, dimeric sulfur monoxide or SO dimer is an oxide of sulfur with the formula S2O2. The solid is unstable with a lifetime of a few seconds at room temperature.

<span class="mw-page-title-main">Nickel sulfide</span> Chemical compound

Nickel sulfide is any inorganic compound with the formula NiSx. These compounds range in color from bronze (Ni3S2) to black (NiS2). The nickel sulfide with simplest stoichiometry is NiS, also known as the mineral millerite. From the economic perspective, Ni9S8, the mineral pentlandite, is the chief source of mined nickel. Other minerals include heazlewoodite (Ni3S2) and polydymite (Ni3S4), and the mineral Vaesite (NiS2). Some nickel sulfides are used commercially as catalysts.

Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermanates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur. Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known,

<span class="mw-page-title-main">Europium(II) oxide</span> Chemical compound

Europium(II) oxide (EuO) is a chemical compound which is one of the oxides of europium. In addition to europium(II) oxide, there is also europium(III) oxide and the mixed valence europium(II,III) oxide.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

Europium(III) iodide is an inorganic compound containing europium and iodine with the chemical formula EuI3.

Lanthanide compounds are compounds formed by the 15 elements classed as lanthanides. The lanthanides are generally trivalent, although some, such as cerium and europium, are capable of forming compounds in other oxidation states.

References

  1. C. Housecroft. Inorganic Chemistry. 3rd. Essex, England: Pearson Education Limited, 2008. Print. ISBN   0-13-175553-6
  2. 1 2 Zhao, Fei; Sun, Hao-Ling; Su, Gang; Gao, Song (2006). "Synthesis and Size-Dependent Magnetic Properties of Monodisperse EuS Nanocrystals". Small. 2 (2). Wiley: 244–248. doi:10.1002/smll.200500294. ISSN   1613-6810. PMID   17193029.
  3. 1 2 3 Ananth, K.P.; Gielisse, P.J.; Rockett, T.J. (1974). "Synthesis and characterization of europium sulfide". Materials Research Bulletin. 9 (9). Elsevier BV: 1167–1171. doi:10.1016/0025-5408(74)90033-6. ISSN   0025-5408.
  4. 1 2 3 Archer, R. D. Mitchel, W. N. Inorganic Syntheses, Europium (II) Sulfide. 1967, volume 10, 77-79. doi : 10.1002/9780470132418
  5. Wells A.F. Structural Inorganic Chemistry. 5th. London, England: Oxford University Press, 1984. Print. ISBN   0-19-855370-6
  6. Manna, Sujit; Wei, Peng; Xie, Yingming; Law, Kam Tuen; Lee, Patrick A.; Moodera, Jagadeesh S. (2020-04-06). "Signature of a pair of Majorana zero modes in superconducting gold surface states". Proceedings of the National Academy of Sciences. 117 (16): 8775–8782. arXiv: 1911.03802 . doi: 10.1073/pnas.1919753117 . ISSN   0027-8424. PMC   7183215 . PMID   32253317.