Tridymite

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Tridymite
Tridymite tabulars - Ochtendung, Eifel, Germany.jpg
Tabular tridymite crystals from Ochtendung, Eifel, Germany
General
Category Oxide mineral (or tectosilicate), quartz group
Formula
(repeating unit)
SiO2
IMA symbol Trd [1]
Strunz classification 4.DA.10
Crystal system Orthorhombic
(α-tridymite)
Crystal class Disphenoidal (222)
H–M symbol: (222)
Space group C2221
Identification
Formula mass 60.08 g/mol
ColorColorless, white
Crystal habit Platy – sheet forms
Cleavage {0001} indistinct, {1010} imperfect
Fracture Brittle – conchoidal
Mohs scale hardness7
Luster Vitreous
Streak white
Specific gravity 2.25–2.28
Optical propertiesBiaxial (+),
2V = 40–86°
Refractive index 'nα=1.468–1.482
nβ=1.470–1.484
nγ=1.474–1.486
Birefringence δ < 0.004
Pleochroism Colorless
Other characteristicsnon-radioactive, non-magnetic; fluorescent, short UV=dark red
References [2] [3]

Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O 2. Tridymite was first described in 1868 and the type location is in Hidalgo, Mexico. The name is from the Greek tridymos for triplet as tridymite commonly occurs as twinned crystal trillings [2] (compound crystals comprising three twinned crystal components).

Contents

Structure

Crystal structure of a-tridymite OC-Tridymite.svg
Crystal structure of α-tridymite
b-tridymite HP-Tridymite.svg
β-tridymite

Tridymite can occur in seven crystalline forms. Two of the most common at standard pressure are known as α and β. The α-tridymite phase is favored at elevated temperatures (above 870 °C) and it converts to β-cristobalite at 1,470 °C. [4] [5] However, tridymite does usually not form from pure β-quartz, one needs to add trace amounts of certain compounds to achieve this. [6] Otherwise the β-quartz-tridymite transition is skipped and β-quartz transitions directly to cristobalite at 1,050 °C without occurrence of the tridymite phase.

Crystal phases of tridymite [5]
NameSymmetry Space group Temp. (°C)
HP (β)HexagonalP63/mmc460
LHPHexagonalP6322400
OC (α)OrthorhombicC2221220
OSOrthorhombic100–200
OPOrthorhombicP212121155
MCMonoclinicCc22
MXMonoclinicC122

In the table, M, O, H, C, P, L and S stand for monoclinic, orthorhombic, hexagonal, centered, primitive, low (temperature) and superlattice. T indicates the temperature, at which the corresponding phase is relatively stable, though the interconversions between phases are complex and sample dependent, and all these forms can coexist at ambient conditions. [5] Mineralogy handbooks often arbitrarily assign tridymite to the triclinic crystal system, yet use hexagonal Miller indices because of the hexagonal crystal shape (see image). [2]

Mars

In December 2015, the team behind NASA's Mars Science Laboratory announced the discovery of large amounts of tridymite in Marias Pass on the slope of Aeolis Mons, popularly known as Mount Sharp, on the planet Mars. [7] This discovery was unexpected given the rarity of the mineral on Earth and the apparent lack of volcanic activity where it was discovered, and at the time of discovery no explanation for how it was formed was forthcoming. Its discovery was serendipitous: two teams, responsible for two different instruments on the Curiosity rover, both happened to report what in isolation were relatively uninteresting findings related to their instruments: the ChemCam team reported a region of high silica while the DAN team reported high neutron readings in what turned out to be the same area. Neither team would have been aware of the other's findings had it not been for a fortuitous Mars conjunction in July 2015, during which the various international teams took advantage of the downtime to meet in Paris and discuss their scientific findings.

DAN's high neutron readings would normally have been interpreted as meaning the region was hydrogen-rich, and ChemCam's high-silica readings were not surprising given the ubiquity of silica-rich deposits on Mars, but taken together it was clear that further study of the region was needed. Following conjunction, NASA directed the Curiosity rover back to the area where the readings had been taken and discovered that large amounts of tridymite were present. How they were formed remains a mystery. [8]

See also

Related Research Articles

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Quartz</span> Mineral made of silicon and oxygen

Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of SiO2. Quartz is, therefore, usually classified as a framework silicate mineral rather than an oxide mineral. Quartz is the second most abundant mineral in Earth's continental crust, behind feldspar.

<span class="mw-page-title-main">Silicon dioxide</span> Oxide of silicon

Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO2, commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is abundant as it comprises several minerals and synthetic products. All forms are white or colorless, although impure samples can be colored.

<span class="mw-page-title-main">Olivine</span> Magnesium iron silicate solid solution series mineral

The mineral olivine is a magnesium iron silicate with the chemical formula (Mg,Fe)2SiO4. It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickly on the surface. For this reason, olivine has been proposed as a good candidate for accelerated weathering to sequester carbon dioxide from the Earth's oceans and atmosphere, as part of climate change mitigation. Olivine also has many other historical uses, such as the gemstone peridot, as well as industrial applications like metalworking processes.

<span class="mw-page-title-main">Orthoclase</span> Tectosilicate mineral found in igneous rock

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.

<span class="mw-page-title-main">Goethite</span> Iron(III) oxide-hydroxide named in honor to the poet Goethe

Goethite is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the α-polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient times for its use as a pigment. Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France. It was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe (1749–1832).

<span class="mw-page-title-main">Sekaninaite</span> Mg, Fe, Al cyclosilicate mineral

Sekaninaite ((Fe+2,Mg)2Al4Si5O18) is a silicate mineral, the iron-rich analogue of cordierite.

<span class="mw-page-title-main">Nepheline</span> Silica-undersaturated aluminosilicate mineral

Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.

<span class="mw-page-title-main">Cristobalite</span> Silica mineral, polymorph of quartz

Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the quartz group, which also include coesite, tridymite and stishovite. It is named after Cerro San Cristóbal in Pachuca Municipality, Hidalgo, Mexico.

<span class="mw-page-title-main">Coesite</span> Silica mineral, rare polymorph of quartz

Coesite is a form (polymorph) of silicon dioxide (SiO2) that is formed when very high pressure (2–3 gigapascals), and moderately high temperature (700 °C, 1,300 °F), are applied to quartz. Coesite was first synthesized by Loring Coes, Jr., a chemist at the Norton Company, in 1953.

<span class="mw-page-title-main">Stishovite</span> Tetragonal form of silicon dioxide

Stishovite is an extremely hard, dense tetragonal form (polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the lower mantle.

<span class="mw-page-title-main">Sanidine</span> Form of potassium feldspar

Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.

<span class="mw-page-title-main">Pyroxferroite</span>

Pyroxferroite (Fe2+,Ca)SiO3 is a single chain inosilicate. It is mostly composed of iron, silicon and oxygen, with smaller fractions of calcium and several other metals. Together with armalcolite and tranquillityite, it is one of the three minerals which were discovered on the Moon during the 1969 Apollo 11 mission. It was then found in Lunar and Martian meteorites as well as a mineral in the Earth's crust. Pyroxferroite can also be produced by annealing synthetic clinopyroxene at high pressures and temperatures. The mineral is metastable and gradually decomposes at ambient conditions, but this process can take billions of years.

The room-temperature form of quartz, α-quartz, undergoes a reversible change in crystal structure at 573 °C to form β-quartz. This phenomenon is called an inversion, and for the α to β quartz inversion is accompanied by a linear expansion of 0.45%. This inversion can lead to cracking of ceramic ware if cooling occurs too quickly through the inversion temperature. This is called dunting, and the resultant faults as dunts. To avoid such thermal shock faults, cooling rates not exceeding 50 °C/hour have been recommended.

<span class="mw-page-title-main">Aeolis quadrangle</span> One of a series of 30 quadrangle maps of Mars

The Aeolis quadrangle is one of a series of 30 quadrangle maps of Mars used by the United States Geological Survey (USGS) Astrogeology Research Program. The Aeolis quadrangle is also referred to as MC-23 . The Aeolis quadrangle covers 180° to 225° W and 0° to 30° south on Mars, and contains parts of the regions Elysium Planitia and Terra Cimmeria. A small part of the Medusae Fossae Formation lies in this quadrangle.

Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid. It is made of white crystals, which have at least three polymorphs and appears in nature as rare minerals cryptohalite or bararite.

Colimaite, the naturally occurring analog of synthetic K3VS4, is a sulfide mineral discovered in southwestern Mexico. The potassium-vanadium sulfide was collected from the crater of the Colima volcano. The mineral colimaite is named after the locality of this volcano and has been approved in 2007, along with its mineral name, by the Commission on New Minerals, Nomenclature and Classification (CNMNC). It has been given the International Mineralogical Association number of IMA 2007–045.

<span class="mw-page-title-main">Seifertite</span> Dense silica mineral

Seifertite is a silicate mineral with the formula SiO2 and is one of the densest polymorphs of silica. It has only been found in Martian and lunar meteorites, where it is presumably formed from either tridymite or cristobalite – other polymorphs of quartz – as a result of heating during the atmospheric re-entry and impact to the Earth, at an estimated minimal pressure of 35 GPa. It can also be produced in the laboratory by compressing cristobalite in a diamond anvil cell to pressures above 40 GPa. The mineral is named after Friedrich Seifert (born 1941), the founder of the Bayerisches Geoinstitut at University of Bayreuth, Germany, and is officially recognized by the International Mineralogical Association.

<span class="mw-page-title-main">Composition of Mars</span> Branch of the geology of Mars

The composition of Mars covers the branch of the geology of Mars that describes the make-up of the planet Mars.

<span class="mw-page-title-main">Guyanaite</span> Chromium oxide mineral

Guyanaite (CrOOH) is a chromium oxide mineral that forms as an intergrowth with other chromium oxide minerals known as bracewellite (CrOOH) and grimaldiite (CrOOH) as well as eskolaite (Cr2O3) which in early findings were nearly indistinguishable from one another. These oxides formed so closely as intergrowths with one another that they were initially, and erroneously, identified as a single definite mineral previously known as merumite. Because of its complex history and the previously undiscovered nature of these chromium oxide polymorphs, the relevance of any information found in many early experiments involving the mineral formerly known as merumite in regard to guyanaite is unknown and it is implied that in any further reference of merumite it will have been composed of a mineral assemblage including guyanaite. The rare occurrence and complexity from intergrowth of naturally occurring guyanaite hinders experimental work, leading to laboratory synthesized samples which help to better experiment with the minerals.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Tridymite". Handbook of Mineralogy (PDF). Vol. III (Halides, Hydroxides, Oxides). Chantilly, VA, US: Mineralogical Society of America. ISBN   0-9622097-2-4 . Retrieved December 5, 2011.
  3. Mindat
  4. Kuniaki Kihara; Matsumoto T.; Imamura M. (1986). "Structural change of orthorhombic-I tridymite with temperature: A study based on second-order thermal-vibrational parameters". Zeitschrift für Kristallographie. 177 (1–2): 27–38. Bibcode:1986ZK....177...27K. doi:10.1524/zkri.1986.177.1-2.27.
  5. 1 2 3 William Alexander Deer; R. A. Howie; W. S. Wise (2004). Rock-Forming Minerals: Framework Silicates: Silica Minerals, Feldspathoids and the Zeolites. Geological Society. p. 22. ISBN   978-1-86239-144-4 . Retrieved 2 January 2012.
  6. Heaney, P. J. (1994). "Structure and chemistry of the low-pressure silica polymorphs". Reviews in Mineralogy. 29.
  7. Chang, Kenneth (December 17, 2015). "Mars Rover Finds Changing Rocks, Surprising Scientists". New York Times . Retrieved December 22, 2015.
  8. Lakdawalla, Emily (December 18, 2015). "Curiosity stories from AGU: The fortuitous find of a puzzling mineral on Mars, and a gap in Gale's history". The Planetary Society . Retrieved December 21, 2015.