Volcanic glass is the amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disordered array of liquid. [1] Volcanic glass may refer to the interstitial material, or matrix, in an aphanitic (fine-grained) volcanic rock, or to any of several types of vitreous igneous rocks.
Volcanic glass is formed when magma is rapidly cooled. Magma rapidly cooled to below its normal crystallization temperature becomes a supercooled liquid, and, with further rapid cooling, this becomes an amorphous solid. The change from supercooled liquid to glass occurs at a temperature called the glass transition temperature, which depends on both cooling rate and the amount of water dissolved in the magma. Magma rich in silica and poor in dissolved water is most easily cooled rapidly enough to form volcanic glass. As a result, rhyolite magmas, which are high in silica, can produce tephra composed entirely of volcanic glass and may also form glassy lava flows. [2] Ash-flow tuffs typically consist of countless microscopic shards of volcanic glass. [3] Basalt, which is low in silica, forms glass only with difficulty, so that basalt tephra almost always contains at least some crystalline material (quench crystals). [2] The glass transition temperature of basalt is about 700 °C (1,292 °F). [4]
The mechanisms controlling formation of volcanic glass are further illustrated by the two forms of basaltic glass, tachylite and sideromelane. Tachylite is opaque to transmitted light because of the abundance of tiny oxide mineral crystals suspended in the glass. Sideromelane is partially transparent because it contains much fewer crystals. Sideromelane is abundant only in eruptions where basalt magma has been very rapidly cooled by contact with water, such as phreatomagmatic eruptions. [5] Basaltic volcanic glass is also present in pillow lavas. [6]
Of the cooling mechanisms responsible for forming volcanic glass, the most effective is quenching by water, followed by cooling by entrained air in an eruption column. The least effective mechanism is cooling at the bottom of a flow in contact with the ground. [4]
Most commonly, volcanic glass refers to obsidian , a rhyolitic glass with high silica (SiO2) content. [7]
Other types of volcanic glass include the following:
Volcanic glass is chemically unstable and readily decomposes. Water molecules readily react with the open, disordered structure of volcanic glass, removing soluble cations from the glass and precipitating secondary ( authigenic ) minerals. As a result, lithification of volcanic ash is one of the fastest low-temperature lithification processes. Alteration of volcanic glass at mid-ocean ridges may have contributed significantly to the formation of massive sulfide deposits, and alteration of volcanic ash beds formed economically important zeolite and bentonite deposits. [9]
A mineraloid is a naturally occurring mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amorphous glass and not a crystal. Jet is derived from decaying wood under extreme pressure. Opal is another mineraloid because of its non-crystalline nature. Pearl is considered a mineraloid because the included calcite and/or aragonite crystals are bonded by an organic material, and there is no definite proportion of the components.
A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface.
Magma is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles.
Basalt is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron exposed at or very near the surface of a rocky planet or moon. More than 90% of all volcanic rock on Earth is basalt. Rapid-cooling, fine-grained basalt is chemically equivalent to slow-cooling, coarse-grained gabbro. The eruption of basalt lava is observed by geologists at about 20 volcanoes per year. Basalt is also an important rock type on other planetary bodies in the Solar System. For example, the bulk of the plains of Venus, which cover ~80% of the surface, are basaltic; the lunar maria are plains of flood-basaltic lava flows; and basalt is a common rock on the surface of Mars.
Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock containing 25% to 75% ash is described as tuffaceous. Tuff composed of sandy volcanic material can be referred to as volcanic sandstone.
Rhyolite is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral assemblage is predominantly quartz, sanidine, and plagioclase. It is the extrusive equivalent to granite.
A stratovolcano, also known as a composite volcano, is a conical volcano built up by many layers (strata) of hardened lava and tephra. Unlike shield volcanoes, stratovolcanoes are characterized by a steep profile with a summit crater and periodic intervals of explosive eruptions and effusive eruptions, although some have collapsed summit craters called calderas. The lava flowing from stratovolcanoes typically cools and hardens before spreading far, due to high viscosity. The magma forming this lava is often felsic, having high to intermediate levels of silica, with lesser amounts of less viscous mafic magma. Extensive felsic lava flows are uncommon, but have travelled as far as 15 km (9 mi).
Extrusive rock refers to the mode of igneous volcanic rock formation in which hot magma from inside the Earth flows out (extrudes) onto the surface as lava or explodes violently into the atmosphere to fall back as pyroclastics or tuff. In contrast, intrusive rock refers to rocks formed by magma which cools below the surface.
Volcanic rock is a rock formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and metamorphic rocks and constitute an important element of some sediments and sedimentary rocks. For these reasons, in geology, volcanics and shallow hypabyssal rocks are not always treated as distinct. In the context of Precambrian shield geology, the term "volcanic" is often applied to what are strictly metavolcanic rocks. Volcanic rocks and sediment that form from magma erupted into the air are called "pyroclastics," and these are also technically sedimentary rocks.
Pyroclastic rocks are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyroclasts. Pyroclastic rocks are a type of volcaniclastic deposit, which are deposits made predominantly of volcanic particles. 'Phreatic' pyroclastic deposits are a variety of pyroclastic rock that forms from volcanic steam explosions and they are entirely made of accidental clasts. 'Phreatomagmatic' pyroclastic deposits are formed from explosive interaction of magma with groundwater.
Ignimbrite is a type of volcanic rock, consisting of hardened tuff. Ignimbrites form from the deposits of pyroclastic flows, which are a hot suspension of particles and gases flowing rapidly from a volcano, driven by being denser than the surrounding atmosphere. New Zealand geologist Patrick Marshall (1869–1950) coined the term ignimbrite from the Latin igni- [fire] and imbri- [rain].
Scoria is a pyroclastic, highly vesicular, dark-colored volcanic rock that was ejected from a volcano as a molten blob and cooled in the air to form discrete grains or clasts. It is typically dark in color, and basaltic or andesitic in composition. Scoria is relatively low in density as a result of its numerous macroscopic ellipsoidal vesicles, but in contrast to pumice, all scoria has a specific gravity greater than 1 and sinks in water.
Palagonite is an alteration product from the interaction of water with volcanic glass of chemical composition similar to basalt. Palagonite can also result from the interaction between water and basalt melt. The water flashes to steam on contact with the hot lava and the small fragments of lava react with the steam to form the light-colored palagonite tuff cones common in areas of basaltic eruptions in contact with water. An example is found in the pyroclastic cones of the Galapagos Islands. Charles Darwin recognized the origin of these cones during his visit to the islands. Palagonite can also be formed by a slower weathering of lava into palagonite, resulting in a thin, yellow-orange rind on the surface of the rock. The process of conversion of lava to palagonite is called palagonitization.
Hyaloclastite is a volcanoclastic accumulation or breccia consisting of glass fragments (clasts) formed by quench fragmentation of lava flow surfaces during submarine or subglacial extrusion. It occurs as thin margins on the lava flow surfaces and between pillow lavas as well as in thicker deposits, more commonly associated with explosive, volatile-rich eruptions as well as steeper topography. Hyaloclastites form during volcanic eruptions under water, under ice or where subaerial flows reach the sea or other bodies of water. It commonly has the appearance of angular flat fragments sized between a millimeter to few centimeters. The fragmentation occurs by the force of the volcanic explosion, or by thermal shock and spallation during rapid cooling.
Sideromelane is a vitreous basaltic volcanic glass, usually occurring in palagonite tuff, for which it is characteristic. It is a less common form of tachylite, with which it usually occurs together; however it lacks the iron oxide crystals dispersed in the glass, and therefore appears transparent and pure, with yellow-brown color, instead of tachylite opaque black. It forms at higher temperatures and with more rapid chilling. Presence of sideromelane indicates higher temperature of the lava, and solidifying of the flow closer to the vent, probably by rapid quenching in a wet environment.
Phreatomagmatic eruptions are volcanic eruptions resulting from interaction between magma and water. They differ from exclusively magmatic eruptions and phreatic eruptions. Unlike phreatic eruptions, the products of phreatomagmatic eruptions contain juvenile (magmatic) clasts. It is common for a large explosive eruption to have magmatic and phreatomagmatic components.
Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or underwater, usually at temperatures from 800 to 1,200 °C. The volcanic rock resulting from subsequent cooling is also often called lava.
Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.
Pahvant Butte is a butte formed by a dormant volcano in the west-central portion of Utah, United States.
Microlites are minute crystals in an amorphous matrix. In igneous petrology, the term microlitic is used to describe vitric matrix containing microscopic crystals. Microlitic rocks are a type of hypocrystalline rocks. Unlike ordinary phenocrysts, which can be seen with little or no magnification, microlites are generally formed in rapidly cooled (quenched) basaltic lava, where cooling rates are too high to permit formation of larger crystals.
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