Bice

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Bice, from the French bis, originally meaning dark-coloured, is a green or blue pigment. In French the terms vert bis and azur bis mean dark green and dark blue respectively. Bice pigments were generally prepared from basic copper carbonates, but sometimes ultramarine or other pigments were used. [1]

Historic usage

In 1522 a stone cross with gilt lead stars was erected at the Bullstake in Canterbury, and painted with bice and gilded by Florence the painter. The bice cost 6 shillings the pound. [2]

Jo Kirby of the National Gallery London notes the occurrence of the pigment bice in three grades in an account of Tudor painting at Greenwich Palace in 1527. In this case, the three grades indicate the use of the mineral azurite rather than a manufactured blue copper carbonate. Similarly, green bice in other 16th-records may sometimes have been the mineral malachite. [3] John "Paynter", who worked for Bess of Hardwick, used blue bice in 1596. [4]

Ian Bristow, a historian of paint, concluded that the pigment blue bice found in records of British interior-decoration until the first half of the 17th century was azurite. The expensive natural mineral azurite was superseded by manufactured blue verditer. [5]

The color is also referenced in Edith Nesbit's novel The Story of the Treasure Seekers : "...Alice looked up from her painting. She was trying to paint a fairy queen's frock with green bice, and it wouldn't rub. There is something funny about green bice. It never will rub off; no matter how expensive your paintbox is-and even boiling water is very little use. She said, ‘Bother the bice’!..." [6]

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3
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Lapis armenus, also known as Armenian stone or lapis stellatus, in natural history, is a variety of precious stone, resembling lapis lazuli, except that it is softer, and instead of veins of pyrite, is intermixed with green. "The Armenian stone" is so similar to lapis lazuli that it has often not been distinguished from it; Webster's Revised Unabridged Dictionary for instance treats the two terms as synonyms. The Dictionary of Traded Goods and Commodities 1550-1820 defines lapis armenus as

Armenian stone, or azurite, a naturally occurring basic copper carbonate, originally from Armenia, but later from Germany, from which blue bice was prepared. It was often found in association with another copper carbonate, malachite from which green bice was prepared... Probably because they were both blue, blue bice was sometimes misinterpreted to mean lapis lazuli.

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<span class="mw-page-title-main">Egyptian blue</span> Pigment used in ancient Egypt

Egyptian blue, also known as calcium copper silicate (CaCuSi4O10 or CaOCuO(SiO2)4 (calcium copper tetrasilicate)) or cuprorivaite, is a pigment that was used in ancient Egypt for thousands of years. It is considered to be the first synthetic pigment. It was known to the Romans by the name caeruleum. After the Roman era, Egyptian blue fell from use and, thereafter, the manner of its creation was forgotten. In modern times, scientists have been able to analyze its chemistry and reconstruct how to make it.

<span class="mw-page-title-main">Chalconatronite</span>

Chalconatronite is a carbonate mineral and rare secondary copper mineral that contains copper, sodium, carbon, oxygen, and hydrogen, its chemical formula is Na2Cu(CO3)2•3(H2O). Chalconatronite is partially soluble in water, and only decomposes, although chalconatronite is soluble while cold, in dilute acids. The name comes from the mineral's compounds, copper ("chalcos" in Greek) and natron, naturally forming sodium carbonate. The mineral is thought to be formed by water carrying alkali carbonates (possibly from soil) reacting with bronze. Similar minerals include malachite, azurite, and other copper carbonates. Chalconatronite has also been found and recorded in Australia, Germany, and Colorado.

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Green pigments are the materials used to create the green colors seen in painting and the other arts. Most come from minerals, particularly those containing compounds of copper. Green pigments reflect the green portions of the spectrum of visible light, and absorb the others. Important green pigments in art history include Malachite and Verdigris, found in tomb paintings in Ancient Egypt, and the Green earth pigments popular in the Middle Ages. More recent greens, such as Cobalt Green, are largely synthetic, made in laboratories and factories.

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Azurite is an inorganic pigment derived from the mineral of the same name. It was likely used by artists as early as the Fourth Dynasty in Egypt, but it was less frequently employed than synthetically produced copper pigments such as Egyptian Blue. In the Middle Ages and Renaissance, it was the most prevalent blue pigment in European paintings, appearing more commonly than the more expensive ultramarine. Azurite's derivation from copper mines tends to give it a greenish hue, in contrast with the more violet tone of ultramarine. Azurite is also less stable than ultramarine, and notable paintings such as Michelangelo's The Entombment have seen their azure blues turn to olive green in time. Azurite pigment typically includes traces of malachite and cuprite; both minerals are found alongside azurite in nature, and they may account for some of the green discoloration of the pigment. The particle size of azurite pigment has been shown to have a significant effect on its chromatic intensity, and the manner of grinding and preparing the pigment therefore has a major impact on its appearance.

References

  1. Wikisource-logo.svg One or more of the preceding sentences incorporates text from a publication now in the public domain :  Chisholm, Hugh, ed. (1911). "Bice". Encyclopædia Britannica . Vol. 3 (11th ed.). Cambridge University Press. p. 911.
  2. HMC 9th Report: Canterbury (London, 1883), p. 150.
  3. Roskill & Hand, ed., Hans Holbein, Paintings, Prints, and Reception (Yale, 2001), p. 119.
  4. Basil Stallybrass, 'Bess of Hardwick's Building Accounts', Archaeologia, 64 (1913), pp. 382–84
  5. Bristow, Ian C., Interior house-Painting Colours and Technology, 1615-1640 (Yale, 1996), p. 17.
  6. Chapter 9 of "The Treasure Seekers" by E.Nesbit