Copperas works

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Copperas house, Limb Valley. Copperas (iron(II) sulfate) was manufactured here from the pyritic Ringinglow coal seam, mined nearby. The copperas solution was used in the leather tanning industry. Copperas house, Limb Valley (geograph 2106189).jpg
Copperas house, Limb Valley. Copperas (iron(II) sulfate) was manufactured here from the pyritic Ringinglow coal seam, mined nearby. The copperas solution was used in the leather tanning industry.

Copperas works are manufactories where copperas (iron(II) sulfate) is produced from pyrite, often obtained as a byproduct during coal mining, and iron. The history of producing green vitriol, as it was known, goes back hundreds of years in Scotland. [1] In 1814 the wool-producing city of Steubenville, Ohio had seven copperas-producing manufacturers. [2]

Pyrite has been used since classical times to manufacture copperas. Iron pyrite was heaped up and allowed to weather (an example of an early form of heap leaching). The acidic runoff from the heap was then boiled with iron to produce iron sulfate. [3] :267 [4] :152–153

Containment of leachate is important due to its toxicity; a fish kill that occurred in the 1890s in the Kanawha River was attributed to copperas solution release from the mines in Cannelton, West Virginia. [5] :282

The "vitriolic waters of Fahlun" (Falun, Sweden), according to Murray (1844), annually produced "about 600 quintals of green vitriol" (sulfate of iron), as well as a "small quantity of blue vitriol" (sulfate of copper). [6] These may have been obtained through evaporation of the groundwater associated with mines in order to yield the crystalline form of copperas. [7]


Related Research Articles

Bioleaching is the extraction of metals from their ores through the use of living organisms. This is much cleaner than the traditional heap leaching using cyanide. Bioleaching is one of several applications within biohydrometallurgy and several methods are used to recover copper, zinc, lead, arsenic, antimony, nickel, molybdenum, gold, silver, and cobalt.

<span class="mw-page-title-main">Gypsum</span> Soft calcium sulfate mineral

Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk chalk. Alabaster, a fine-grained white or lightly tinted variety of gypsum, has been used for sculpture by many cultures including Ancient Egypt, Mesopotamia, Ancient Rome, the Byzantine Empire, and the Nottingham alabasters of Medieval England. Gypsum also crystallizes as translucent crystals of selenite. It forms as an evaporite mineral and as a hydration product of anhydrite.

<span class="mw-page-title-main">Sulfuric acid</span> Chemical compound (H₂SO₄)

Sulfuric acid or sulphuric acid, known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula H2SO4. It is a colorless, odorless, and viscous liquid that is miscible with water.

<span class="mw-page-title-main">Pyrite</span> Iron (II) disulfide mineral

The mineral pyrite, or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula FeS2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.

<span class="mw-page-title-main">Iron(II) sulfate</span> Chemical compound

Iron(II) sulfate (British English: iron(II) sulphate) or ferrous sulfate denotes a range of salts with the formula Fe SO4·xH2O. These compounds exist most commonly as the heptahydrate (x = 7) but several values for x are known. The hydrated form is used medically to treat iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol (vitriol is an archaic name for sulfate), the blue-green heptahydrate (hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex [Fe(H2O)6]2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas.

<span class="mw-page-title-main">Chalcopyrite</span> Copper iron sulfide mineral

Chalcopyrite ( KAL-kə-PY-ryte, -⁠koh-) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black.

<span class="mw-page-title-main">Gallic acid</span> 3,4,5-Trihydroxybenzoic acid

Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6H2(OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plants. It is a white solid, although samples are typically brown owing to partial oxidation. Salts and esters of gallic acid are termed "gallates".

<span class="mw-page-title-main">Wheellock</span> Firearm action

A wheellock, wheel-lock, or wheel lock is a friction-wheel mechanism which creates a spark that causes a firearm to fire. It was the next major development in firearms technology after the matchlock and the first self-igniting firearm. Its name is from its rotating steel wheel to provide ignition. Developed in Europe around 1500, it was used alongside the matchlock and later the snaplock (1540s), the snaphance (1560s), and the flintlock.

<span class="mw-page-title-main">Copper(II) sulfate</span> Chemical compound

Copper(II) sulfate, also known as copper sulphate, is an inorganic compound with the chemical formula CuSO4. It forms hydrates CuSO4·nH2O, where n can range from 1 to 7. The pentahydrate (n = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate. Older names for the pentahydrate include blue vitriol, bluestone, vitriol of copper, and Roman vitriol. It exothermically dissolves in water to give the aquo complex [Cu(H2O)6]2+, which has octahedral molecular geometry. The structure of the solid pentahydrate reveals a polymeric structure wherein copper is again octahedral but bound to four water ligands. The Cu(II)(H2O)4 centers are interconnected by sulfate anions to form chains. Anhydrous copper sulfate is a light grey powder.

<span class="mw-page-title-main">Jarosite</span> Alunite supergroup, potassium iron basic sulfate mineral

Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct during the purification and refining of zinc and is also commonly associated with acid mine drainage and acid sulfate soil environments.

<span class="mw-page-title-main">Acid mine drainage</span> Outflow of acidic water from metal or coal mines

Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines or coal mines.

Green Pond is a private lakeside residential unincorporated community within Rockaway Township in Morris County, New Jersey, United States. The lakeside community is managed by two corporations, Green Pond Corporation and Lake End Corporation.

<span class="mw-page-title-main">Marcasite</span> Iron disulfide (FeS2) with orthorhombic crystal structure

The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures contain the disulfide S22− ion, having a short bonding distance between the sulfur atoms. The structures differ in how these di-anions are arranged around the Fe2+ cations. Marcasite is lighter and more brittle than pyrite. Specimens of marcasite often crumble and break up due to the unstable crystal structure.

<span class="mw-page-title-main">Heap leaching</span> Industrial mining process used to extract precious metals from ore

Heap leaching is an industrial mining process used to extract precious metals, copper, uranium, and other compounds from ore using a series of chemical reactions that absorb specific minerals and re-separate them after their division from other earth materials. Similar to in situ mining, heap leach mining differs in that it places ore on a liner, then adds the chemicals via drip systems to the ore, whereas in situ mining lacks these liners and pulls pregnant solution up to obtain the minerals. Heap leaching is widely used in modern large-scale mining operations as it produces the desired concentrates at a lower cost compared to conventional processing methods such as flotation, agitation, and vat leaching.

<i>Ferroplasma</i> Genus of archaea

Ferroplasma is a genus of Archaea that belong to the family Ferroplasmaceae. Members of the Ferroplasma are typically acidophillic, pleomorphic, irregularly shaped cocci.

Acid sulfate soils are naturally occurring soils, sediments or organic substrates that are formed under waterlogged conditions. These soils contain iron sulfide minerals and/or their oxidation products. In an undisturbed state below the water table, acid sulfate soils are benign. However, if the soils are drained, excavated or otherwise exposed to air, the sulfides react with oxygen to form sulfuric acid.

<span class="mw-page-title-main">Trough Creek State Park</span> State park in Huntingdon County, Pennsylvania

Trough Creek State Park is a 554 acres (224 ha) Pennsylvania state park in Cass, Penn and Todd Townships, Huntingdon County, Pennsylvania in the United States. The majority of the park is in Todd Township along Pennsylvania Route 994, east of the unincorporated village of Entriken. Huntingdon is the nearest borough. The park borders Rothrock State Forest and Raystown Lake National Recreation Area. There is a growing population of bald eagles at the lake. Fourteen eagles were spotted in January 2007. This is up from two that were spotted in 1990, the first year that an eagle survey was taken. These three sections of state and federal owned property combine together to provide hunting, hiking and fishing opportunities for the outdoorsman.

<span class="mw-page-title-main">Iron Mountain Mine</span>

Iron Mountain Mine, also known as the Richmond Mine at Iron Mountain, is a mine near Redding in Northern California, US. Geologically classified as a "massive sulfide ore deposit", the site was mined for iron, silver, gold, copper, zinc, quartz, and pyrite intermittently from the 1860s until 1963. The mine is the source of extremely acidic mine drainage which also contains large amounts of zinc, copper and cadmium. One of America's most toxic waste sites, it has been listed as a federal Superfund site since 1983.

<span class="mw-page-title-main">Coccinite</span>

Coccinite is a rare mercury iodide mineral with chemical formula of HgI2, mercury(II) iodide. It was first discovered in Casas Viejas, Mexico; it has also been reported from Broken Hill, New South Wales, and from a uranium mine in Thuringia and old mercury workings in the Rhineland-Palatinate in Germany. At the Thuringia deposit the mineral occurs as a sublimation product resulting from fires associated with pyrite-bearing graptolitic slate.

References

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  2. Sears, Robert, ed. (1848). A New and Popular Pictorial Description of the United States. New York: Robert Sears. pp. 506–508. Retrieved 30 December 2022 via Internet Archive.
  3. "Industrial England in the Middle of the Eighteenth Century". Nature. 83 (2113): 264–268. 1910-04-28. Bibcode:1910Natur..83..264.. doi: 10.1038/083264a0 . S2CID   34019869.
  4. Wood, Henry Trueman (1910). "Chapter 6". Industrial England in the Middle of the Eighteenth Century. London: John Murray. pp. 129–157. hdl: 2027/coo1.ark:/13960/t63497b2h . Retrieved 30 December 2022 via Internet Archive.
  5. Evermann, Barton Warren (1902). "Description of a New Species of Shad (Alosa ohiensis), with Notes on Other Food-Fishes of the Ohio River" (PDF). In Bowers, George M. (ed.). U.S. Commission of Fish and Fisheries, George M. Bowers, Commissioner, Part 27: Report of the Commissioner for the Year Ending June 30, 1901. Washington: Government Printing Office. pp. 275–288. Retrieved 30 December 2022 via Penobscot Bay Watch.
  6. Murray, Hugh (1844). "Part III, Book I, Chapter 15, Entry 3257. Sulphur and vitriol". The Encyclopædia of Geography: Comprising a Complete Description of the Earth, Physical, Statistical, Civil, and Political (Second ed.). London: Longman, Brown, Green, and Longmans. p. 768. Retrieved 30 December 2022 via Google Books.
  7. Helm-Clark, C.M. (28 October 2017). "Green Vitriol". The Gnarly Science Blog. Retrieved 30 December 2022.