List of S-phrases

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S-phrases were defined in Annex IV:Safety advice concerning dangerous substances and preparations of the European Union Directive 67/548/EEC - Dangerous Substances Directive. The list was consolidated and republished in Directive 2001/59/EC, where translations into other EU languages may be found. The list was subsequently updated and republished in Directive 2006/102/EC, where translations to additional European languages were added. [1] The entirety of Directive 67/548/EEC, including these S-phrases, were superseded completely on 1 June 2015 by Regulation (EC) No 1272/2008 - Classification, Labelling and Packaging Regulations. [2]

Contents

These safety phrases were used internationally and not just in Europe, and there is an ongoing effort towards complete international harmonization. This harmonization would be carried out by the United Nations's Globally Harmonized System of Classification and Labelling of Chemicals, that replaced Directive 67/548/EEC under CLP Regulation. S-Phrases successor in GHS were GHS precautionary statements, which encompasses both s-phrases and R-phrases. [3] [2]

Safety phrases

CodePhrase
S1Keep locked up.
S2Keep out of the reach of children.
S3Keep in a cool place.
S4Keep away from living quarters.
S5Keep contents under ... (appropriate liquid to be specified by the manufacturer).
S6Keep under ... (inert gas to be specified by the manufacturer).
S7Keep container tightly closed.
S8Keep container dry.
S9Keep container in a well-ventilated place.
S10Keep contents wet. (No longer used, removed from regulations)
S11Avoid contact with air. (No longer used, removed from regulations)
S12Do not keep the container sealed
S13Keep away from food, drink and animal feedingstuffs.
S14Keep away from ... (incompatible materials to be indicated by the manufacturer)
S15Keep away from heat.
S16Keep away from sources of ignition - No smoking.
S17Keep away from combustible material.
S18Handle and open container with care.
S20When using do not eat or drink.
S21When using do not smoke.
S22Do not breathe dust.
S23Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
S24Avoid contact with skin.
S25Avoid contact with eyes.
S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27Take off immediately all contaminated clothing.
S28After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
S29Do not empty into drains.
S30Never add water to this product.
S33Take precautionary measures against static discharges. (No longer used, removed from regulations)
S34Avoid strokes and frictions. (No longer used, removed from regulations)
S35This material and its container must be disposed of in a safe way.
S36Wear suitable protective clothing.
S37Wear suitable gloves.
S38In case of insufficient ventilation wear suitable respiratory equipment.
S39Wear eye/face protection.
S40To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer).
S41In case of fire and/or explosion do not breathe fumes.
S42During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified by the manufacturer).
S43In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water).
S44If you feel unwell, seek medical advice immediately. (Show the label where possible.) (No longer used, removed from regulations)
S45In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
S46If swallowed, seek medical advice immediately and show this container or label.
S47Keep at temperature not exceeding ... °C (to be specified by the manufacturer).
S48Keep wet with ... (appropriate material to be specified by the manufacturer).
S49Keep only in the original container.
S50Do not mix with ... (to be specified by the manufacturer).
S51Use only in well-ventilated areas.
S52Not recommended for interior use on large surface areas.
S53Avoid exposure - obtain special instructions before use.
S54Before draining of to sewage disposal plant ask permission of the competent authority. (No longer used, removed from regulations)
S55Before draining of into sewage system or into waters treat according to state of art. (No longer used, removed from regulations)
S56Dispose of this material and its container at hazardous or special waste collection point.
S57Use appropriate containment to avoid environmental contamination.
S58Dispose as hazardous waste. (No longer used, removed from regulations)
S59Refer to manufacturer/supplier for information on recovery/recycling.
S60This material and its container must be disposed of as hazardous waste.
S61Avoid release to the environment. Refer to special instructions/safety data sheet.
S62If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible.
S63In case of accident by inhalation: remove casualty to fresh air and keep at rest.
S64If swallowed, rinse mouth with water (only if the person is conscious).
Combinations of S phrases.
S1/2Keep locked up and out of the reach of children.
S3/7Keep container tightly closed in a cool place.
S3/7/9Keep container tightly closed in a cool, well-ventilated place. (No longer used, removed from regulations)
S3/9/14Keep in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer).
S3/9/14/49Keep only in the original container in a cool, well-ventilated place away from ... (incompatible materials to be indicated by the manufacturer).
S3/9/49Keep only in the original container in a cool, well-ventilated place.
S3/14Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer).
S7/8Keep container tightly closed and dry.
S7/9Keep container tightly closed and in a well-ventilated place.
S7/47Keep container tightly closed and at temperature not exceeding ... °C (to be specified by the manufacturer).
S20/21When using do not eat, drink or smoke.
S24/25Avoid contact with skin and eyes.
S27/28After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of ... (to be specified by the manufacturer).
S29/35Do not empty into drains; dispose of this material and its container in a safe way.
S29/56Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
S36/37Wear suitable protective clothing and gloves.
S36/37/39Wear suitable protective clothing, gloves and eye/face protection.
S36/39Wear suitable protective clothing and eye/face protection.
S37/39Wear suitable gloves and eye/face protection.
S47/49Keep only in the original container at temperature not exceeding ... °C (to be specified by the manufacturer).

See also

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References

  1. Council of the European Union (20 November 2006). "Council Directive 2006/102/EC of 20 November 2006 adapting Directive 67/548/EEC on the classification, packaging and labelling of dangerous substances". eur-lex.europa.eu. Publications Office of the European Union. Retrieved 25 August 2023. Annex IV - Safety advice concerning dangerous substances and preparations
  2. 1 2 Council of the European Union (16 December 2008). "Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006". eur-lex.europa.eu. Publications Office of the European Union. Retrieved 25 August 2023.
  3. United Nations (2021). "Globally Harmonized System of Classification and Labelling of Chemicals (GHS)" (PDF). unece.org. United Nations. pp. 263–378. Archived from the original (PDF) on 19 November 2021. Retrieved 26 August 2023. Annex 3 - Codification of Hazard Statements, Codification, and Use of Precautionary Statements, Codification of Hazard Pictograms and Examples of Precautionary Pictograms