| Discipline | Chemistry |
|---|---|
| Language | English |
| Publication details | |
| History | 1960 to present |
| Publisher | |
| Frequency | Monthly |
| 1.8 (2022) | |
| Standard abbreviations | |
| ISO 4 | Pure Appl. Chem. |
| Indexing | |
| ISSN | 1365-3075 |
| Links | |
Pure and Applied Chemistry is the official journal for the International Union of Pure and Applied Chemistry (IUPAC). [1] It is published monthly by Walter de Gruyter and contains recommendations and reports, and lectures from symposia.
The International Union of Pure and Applied Chemistry is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is a member of the International Science Council (ISC). IUPAC is registered in Zürich, Switzerland, and the administrative office, known as the "IUPAC Secretariat", is in Research Triangle Park, North Carolina, United States. IUPAC's executive director heads this administrative office, currently Greta Heydenrych.
In chemistry, an enantiomer – also called optical isomer, antipode, or optical antipode – is one of two stereoisomers that are nonsuperposable onto their own mirror image. Enantiomers of each other are much like one's right and left hands; without mirroring one of them, hands cannot be superposed onto each other. It is solely a relationship of chirality and the permanent three-dimensional relationships among molecules or other chemical structures: no amount of re-orientiation of a molecule as a whole or conformational change converts one chemical into its enantiomer. Chemical structures with chirality rotate plane-polarized light. A mixture of equal amounts of each enantiomer, a racemic mixture or a racemate, does not rotate light.
Relative atomic mass, also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a given sample to the atomic mass constant. The atomic mass constant is defined as being 1/12 of the mass of a carbon-12 atom. Since both quantities in the ratio are masses, the resulting value is dimensionless. These definitions remain valid even after the 2019 redefinition of the SI base units.
Chemical species are a specific form of chemical substance or chemically identical molecular entities that have the same molecular energy level at a specified timescale. These entities are classified through bonding types and relative abundance of isotopes. Types of chemical species can be classified based on the type of molecular entity and can be either an atomic, molecular, ionic or radical species.
There are seven stable isotopes of mercury (80Hg) with 202Hg being the most abundant (29.86%). The longest-lived radioisotopes are 194Hg with a half-life of 444 years, and 203Hg with a half-life of 46.612 days. Most of the remaining 40 radioisotopes have half-lives that are less than a day. 199Hg and 201Hg are the most often studied NMR-active nuclei, having spin quantum numbers of 1/2 and 3/2 respectively. All isotopes of mercury are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed. These isotopes are predicted to undergo either alpha decay or double beta decay.
Gold (79Au) has one stable isotope, 197Au, and 37 radioisotopes, with 195Au being the most stable with a half-life of 186 days. Gold is currently considered the heaviest monoisotopic element. Bismuth formerly held that distinction until alpha-decay of the 209Bi isotope was observed. All isotopes of gold are either radioactive or, in the case of 197Au, observationally stable, meaning that 197Au is predicted to be radioactive but no actual decay has been observed.
Natural holmium (67Ho) contains one observationally stable isotope, 165Ho. The below table lists 36 isotopes spanning 140Ho through 175Ho as well as 33 nuclear isomers. Among the known synthetic radioactive isotopes; the most stable one is 163Ho, with a half-life of 4,570 years. All other radioisotopes have half-lives not greater than 1.117 days in their ground states, and most have half-lives under 3 hours.
Naturally occurring rhodium (45Rh) is composed of only one stable isotope, 103Rh. The most stable radioisotopes are 101Rh with a half-life of 3.3 years, 102Rh with a half-life of 207 days, and 99Rh with a half-life of 16.1 days. Thirty other radioisotopes have been characterized with atomic weights ranging from 88.949 u (89Rh) to 121.943 u (122Rh). Most of these have half-lives that are less than an hour except 100Rh and 105Rh. There are also numerous meta states with the most stable being 102mRh (0.141 MeV) with a half-life of about 3.7 years and 101mRh (0.157 MeV) with a half-life of 4.34 days.
Chemical nomenclature is a set of rules to generate systematic names for chemical compounds. The nomenclature used most frequently worldwide is the one created and developed by the International Union of Pure and Applied Chemistry (IUPAC).
The standard atomic weight of a chemical element (symbol Ar°(E) for element "E") is the weighted arithmetic mean of the relative isotopic masses of all isotopes of that element weighted by each isotope's abundance on Earth. For example, isotope 63Cu (Ar = 62.929) constitutes 69% of the copper on Earth, the rest being 65Cu (Ar = 64.927), so
In chemical nomenclature, a preferred IUPAC name (PIN) is a unique name, assigned to a chemical substance and preferred among all possible names generated by IUPAC nomenclature. The "preferred IUPAC nomenclature" provides a set of rules for choosing between multiple possibilities in situations where it is important to decide on a unique name. It is intended for use in legal and regulatory situations.
Nomenclature of Organic Chemistry, commonly referred to by chemists as the Blue Book, is a collection of recommendations on organic chemical nomenclature published at irregular intervals by the International Union of Pure and Applied Chemistry (IUPAC). A full edition was published in 1979, an abridged and updated version of which was published in 1993 as A Guide to IUPAC Nomenclature of Organic Compounds. Both of these are now out-of-print in their paper versions, but are available free of charge in electronic versions. After the release of a draft version for public comment in 2004 and the publication of several revised sections in the journal Pure and Applied Chemistry, a fully revised edition was published in print in 2013 and its online version is also available.
The Compendium of Analytical Nomenclature is an IUPAC nomenclature book published by the International Union of Pure and Applied Chemistry (IUPAC) containing internationally accepted definitions for terms in analytical chemistry. It has traditionally been published in an orange cover, hence its informal name, the Orange Book.
The International Union of Pure and Applied Chemistry (IUPAC) publishes many books which contain its complete list of definitions. The definitions are divided initially into seven IUPAC Colour Books: Gold, Green, Blue, Purple, Orange, White, and Red. There is also an eighth book, the "Silver Book".
The IUPAC/IUPAP Joint Working Party is a group convened periodically by the International Union of Pure and Applied Chemistry (IUPAC) and the International Union of Pure and Applied Physics (IUPAP) to consider claims for discovery and naming of new chemical elements. It is sometimes called the Joint Working Party on Discovery of Elements. The working party's recommendations are voted on by the General Assembly of the IUPAP.
The Commission on Isotopic Abundances and Atomic Weights (CIAAW) is an international scientific committee of the International Union of Pure and Applied Chemistry (IUPAC) under its Division of Inorganic Chemistry. Since 1899, it is entrusted with periodic critical evaluation of atomic weights of chemical elements and other cognate data, such as the isotopic composition of elements. The biennial CIAAW Standard Atomic Weights are accepted as the authoritative source in science and appear worldwide on the periodic table wall charts.
The International IUPAC Conferences on Green Chemistry (ICGCs) gather several hundreds scientists, technologists, and experts from all over the world with the aim to exchange and disseminate new ideas, discoveries, and projects on green chemistry and a sustainable development. After mid twentieth century, an increasingly general consensus acknowledges that these subjects play a unique role in mapping the way ahead for the humankind progress. Typical topics discussed in these IUPAC Conferences are:
The International Union of Pure and Applied Chemistry (IUPAC) has published four sets of rules to standardize chemical nomenclature.
Mary Jean Garson is an organic chemist and academic in Australia. She currently works for the University of Queensland.
Chemistry International is a news magazine published by the International Union of Pure and Applied Chemistry (IUPAC). According to its website, it was originally published in editions covering two months at a time. In 2017 the magazine began to be published quarterly, and as of 2022, the print edition was discontinued in favor of freely accessible online editions.
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