Ductile iron

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Ductile iron, also known as ductile cast iron, nodular cast iron, spheroidal graphite iron, spheroidal graphite cast iron [1] and SG iron, is a type of graphite-rich cast iron discovered in 1943 by Keith Millis. [2] While most varieties of cast iron are weak in tension and brittle, ductile iron has much more impact and fatigue resistance, due to its nodular graphite inclusions.

Contents

Augustus F. Meehan was awarded U.S. patent 1,790,552 in January 1931 for inoculating iron with calcium silicide to produce ductile iron subsequently licensed as Meehanite, still produced as of 2024. In October 1949 Keith Dwight Millis, Albert Paul Gagnebin and Norman Boden Pilling, all working for INCO, received U.S. patent 2,485,760 on a cast ferrous alloy using magnesium for ductile iron production. [3]

Metallurgy

Etched and polished ductile iron microstructure at 100x magnification, showing carbon islanding effect around nodules. Ductile Iron.png
Etched and polished ductile iron microstructure at 100× magnification, showing carbon islanding effect around nodules.
Another micrograph showing the carbon islanding effect, with nodules surrounded by areas depleted of carbon Gusseisen mit Kugelgraphit.jpg
Another micrograph showing the carbon islanding effect, with nodules surrounded by areas depleted of carbon

Ductile iron is not a single material but part of a group of materials which can be produced with a wide range of properties through control of their microstructure. The common defining characteristic of this group of materials is the shape of the graphite. In ductile irons, graphite is in the form of nodules rather than flakes as in grey iron. Whereas sharp graphite flakes create stress concentration points within the metal matrix, rounded nodules inhibit the creation of cracks, thus providing the enhanced ductility that gives the alloy its name. [5] Nodule formation is achieved by adding nodulizing elements, most commonly magnesium (magnesium boils at 1100 °C and iron melts at 1500 °C) and, less often now, cerium (usually in the form of mischmetal). [6] Tellurium has also been used. Yttrium, often a component of mischmetal, has also been studied as a possible nodulizer.

Austempered ductile iron (ADI; i.e., austenite tempered [7] ) was discovered in the 1950s but was commercialized and achieved success only some years later. In ADI, the metallurgical structure is manipulated through a sophisticated heat treating process.[ citation needed ]

Composition

Mass fraction (%) for ferritic ductile iron castings [8]
Fe C Si Ni Mn Mg Cr P S Cu
Balance3.0–3.71.2–2.31.00.250.070.070.030.1
Balance3.3–3.62.2–2.80.1-0.20.03–0.040.005–0.040.005–0.02<0.40

Elements such as copper or tin may be added to increase tensile and yield strength while simultaneously reducing ductility. Improved corrosion resistance can be achieved by replacing 15–30% of the iron in the alloy with varying amounts of nickel, copper, or chromium. Other ductile iron compositions often have a small amount of sulfur as well.

Silicon as a graphite formation element can be partially replaced by aluminum to provide better oxidation protection. [9]

Applications

Cast-iron "no hub" drain waste and vent (DWV) piping Cast fe and cu dwv piping.jpg
Cast-iron "no hub" drain waste and vent (DWV) piping
Cast iron "harp" of a grand piano Fluegel-Rahmen.jpg
Cast iron "harp" of a grand piano

Much of the annual production of ductile iron is in the form of ductile iron pipe, used for water and sewer lines. It competes with polymeric materials such as PVC, HDPE, LDPE and polypropylene, which are all much lighter than steel or ductile iron; being softer and weaker, these require protection from physical damage.

Ductile iron is specifically useful in many automotive components, where strength must surpass that of aluminum but more expensive steel is not necessarily required. Other major industrial applications include off-highway diesel trucks, class 8 trucks, agricultural tractors, and oil well pumps. In the wind power industry ductile iron is used for hubs and structural parts like machine frames. Ductile iron is suitable for large and complex shapes and high (fatigue) loads.

Ductile iron is used in many piano harps (the iron plates which anchor piano strings).

Ductile iron is used for vises. Previously, regular cast iron or steel was commonly used. The properties of ductile iron make it a significant upgrade in strength and durability from cast iron without having to use steel, which is expensive and has poor castability.

See also

Related Research Articles

<span class="mw-page-title-main">Cast iron</span> Iron-carbon alloys with a carbon content more than 2% and silicon content between 1 and 3%

Cast iron is a class of iron–carbon alloys with a carbon content of more than 2% and silicon content around 1–3%. Its usefulness derives from its relatively low melting temperature. The alloying elements determine the form in which its carbon appears: white cast iron has its carbon combined into an iron carbide named cementite, which is very hard, but brittle, as it allows cracks to pass straight through; grey cast iron has graphite flakes which deflect a passing crack and initiate countless new cracks as the material breaks, and ductile cast iron has spherical graphite "nodules" which stop the crack from further progressing.

Beryllium copper (BeCu), also known as copper beryllium (CuBe), beryllium bronze, and spring copper, is a copper alloy with 0.5–3% beryllium. Copper beryllium alloys are often used because of their high strength and good conductivity of both heat and electricity. It is used for its ductility, weldability in metalworking, and machining properties. It has many specialized applications in tools for hazardous environments, musical instruments, precision measurement devices, bullets, and some uses in the field of aerospace. Beryllium copper and other beryllium alloys are harmful carcinogens that present a toxic inhalation hazard during manufacturing.

<span class="mw-page-title-main">Heat treating</span> Process of heating something to alter it

Heat treating is a group of industrial, thermal and metalworking processes used to alter the physical, and sometimes chemical, properties of a material. The most common application is metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve the desired result such as hardening or softening of a material. Heat treatment techniques include annealing, case hardening, precipitation strengthening, tempering, carburizing, normalizing and quenching. Although the term heat treatment applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes such as hot forming or welding.

<span class="mw-page-title-main">Austenite</span> Metallic, non-magnetic allotrope of iron or a solid solution of iron, with an alloying element

Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. In plain-carbon steel, austenite exists above the critical eutectoid temperature of 1000 K (727 °C); other alloys of steel have different eutectoid temperatures. The austenite allotrope is named after Sir William Chandler Roberts-Austen (1843–1902). It exists at room temperature in some stainless steels due to the presence of nickel stabilizing the austenite at lower temperatures.

<span class="mw-page-title-main">Carbon steel</span> Steel in which the main interstitial alloying constituent is carbon

Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states:

Keith Dwight Millis was an American metallurgical engineer and inventor of ductile iron.

<span class="mw-page-title-main">Tempering (metallurgy)</span> Process of heat treating used to increase the toughness of iron-based alloys

Tempering is a process of heat treating, which is used to increase the toughness of iron-based alloys. Tempering is usually performed after hardening, to reduce some of the excess hardness, and is done by heating the metal to some temperature below the critical point for a certain period of time, then allowing it to cool in still air. The exact temperature determines the amount of hardness removed, and depends on both the specific composition of the alloy and on the desired properties in the finished product. For instance, very hard tools are often tempered at low temperatures, while springs are tempered at much higher temperatures.

<span class="mw-page-title-main">Gray iron</span> Alloy of iron and carbon

Gray iron, or grey cast iron, is a type of cast iron that has a graphitic microstructure. It is named after the gray color of the fracture it forms, which is due to the presence of graphite. It is the most common cast iron and the most widely used cast material based on weight.

<span class="mw-page-title-main">Malleable iron</span>

Malleable iron is cast as white iron, the structure being a metastable carbide in a pearlitic matrix. Through an annealing heat treatment, the brittle structure as first cast is transformed into the malleable form. Carbon agglomerates into small roughly spherical aggregates of graphite, leaving a matrix of ferrite or pearlite according to the exact heat treatment used.

<span class="mw-page-title-main">Ferrosilicon</span> Alloy of silicon and iron

Ferrosilicon is an alloy of iron and silicon with a typical silicon content by weight of 15–90%. It contains a high proportion of iron silicides.

In metallurgy and materials science, annealing is a heat treatment that alters the physical and sometimes chemical properties of a material to increase its ductility and reduce its hardness, making it more workable. It involves heating a material above its recrystallization temperature, maintaining a suitable temperature for an appropriate amount of time and then cooling.

<span class="mw-page-title-main">Aluminium alloy</span> Alloy in which aluminium is the predominant metal

An aluminium alloy (UK/IUPAC) or aluminum alloy is an alloy in which aluminium (Al) is the predominant metal. The typical alloying elements are copper, magnesium, manganese, silicon, tin, nickel and zinc. There are two principal classifications, namely casting alloys and wrought alloys, both of which are further subdivided into the categories heat-treatable and non-heat-treatable. About 85% of aluminium is used for wrought products, for example rolled plate, foils and extrusions. Cast aluminium alloys yield cost-effective products due to the low melting point, although they generally have lower tensile strengths than wrought alloys. The most important cast aluminium alloy system is Al–Si, where the high levels of silicon (4–13%) contribute to give good casting characteristics. Aluminium alloys are widely used in engineering structures and components where light weight or corrosion resistance is required.

6061 aluminium alloy is a precipitation-hardened aluminium alloy, containing magnesium and silicon as its major alloying elements. Originally called "Alloy 61S", it was developed in 1935. It has good mechanical properties, exhibits good weldability, and is very commonly extruded. It is one of the most common alloys of aluminium for general-purpose use.

7075 aluminium alloy (AA7075) is an aluminium alloy with zinc as the primary alloying element. It has excellent mechanical properties and exhibits good ductility, high strength, toughness, and good resistance to fatigue. It is more susceptible to embrittlement than many other aluminium alloys because of microsegregation, but has significantly better corrosion resistance than the alloys from the 2000 series. It is one of the most commonly used aluminium alloys for highly stressed structural applications and has been extensively used in aircraft structural parts.

<span class="mw-page-title-main">Austempering</span>

Austempering is heat treatment that is applied to ferrous metals, most notably steel and ductile iron. In steel it produces a bainite microstructure whereas in cast irons it produces a structure of acicular ferrite and high carbon, stabilized austenite known as ausferrite. It is primarily used to improve mechanical properties or reduce / eliminate distortion. Austempering is defined by both the process and the resultant microstructure. Typical austempering process parameters applied to an unsuitable material will not result in the formation of bainite or ausferrite and thus the final product will not be called austempered. Both microstructures may also be produced via other methods. For example, they may be produced as-cast or air cooled with the proper alloy content. These materials are also not referred to as austempered.

5154 aluminium alloy is an alloy in the wrought aluminium-magnesium family. As an aluminium-magnesium alloy, it combines moderate-to-high strength with excellent weldability. 5154 aluminium is commonly used in welded structures such as pressure vessels and ships. As a wrought alloy, it can be formed by rolling, extrusion, and forging, but not casting. It can be cold worked to produce tempers with a higher strength but a lower ductility. It is generally not clad.

5454 aluminium–magnesium alloy is an alloy in the wrought aluminium-magnesium family. It is closely related to 5154 aluminium alloy. As an aluminium-magnesium alloy, it combines moderate-to-high strength with excellent weldability. Like 5154, 5454 aluminium is commonly used in welded structures such as pressure vessels and ships. As a wrought alloy, it can be formed by rolling, extrusion, and forging, but not casting. It can be cold worked to produce tempers with a higher strength but a lower ductility. It is generally not clad.

5456 aluminium–magnesium alloy is an alloy in the wrought aluminium-magnesium family. While it is closely related to 5356 aluminium alloy, it is used in structural applications, like most other aluminium-magnesium alloys, and not as filler for welding. As a wrought alloy, it can be formed by rolling, extrusion, and forging, but not casting. It can be cold worked to produce tempers with a higher strength but a lower ductility. It is susceptible to exfoliation corrosion when held at temperatures above 65 °C (150 °F) for extended periods of time.

<span class="mw-page-title-main">Austempered Ductile Iron</span>

Austempered Ductile Iron (ADI) is a form of ductile iron that enjoys high strength and ductility as a result of its microstructure controlled through heat treatment. While conventional ductile iron was discovered in 1943 and the austempering process had been around since the 1930s, the combination of the two technologies was not commercialized until the 1970s.

AlSi10Mg is a lightweight, high-strength aluminium alloy that is widely used in the aerospace, automotive, and medical industries. Its unique combination of aluminium, silicon, and magnesium makes it an ideal material for additive manufacturing processes, such as 3D printing.

References

  1. Smith & Hashemi 2006 , p. 432.
  2. "Modern Casting, Inc". Archived from the original on 2004-12-14. Retrieved 2005-01-01.
  3. USpatent 2485760,Keith Millis,"Cast Ferrous Alloy",issued 1949-10-25
  4. Yaqub, Ejaz; Arshad, Rizwan (2009). "ME-140 Workshop Technology - Slide 25" (images). Air University. Retrieved 2011-10-30.
  5. "Ductile Iron Data - Section 2". www.ductile.org. Archived from the original on 2001-01-29.
  6. Gillespie, LaRoux K. (1988), Troubleshooting manufacturing processes (4th ed.), SME, p. 4-4, ISBN   978-0-87263-326-1.
  7. "ADI the Material". ADI Treatments Ltd. Archived from the original on 2010-10-26. Retrieved 2010-01-24.
  8. ASTM International. A874/A874M-98(2018)e1 Standard Specification for Ferritic Ductile Iron Castings Suitable for Low-Temperature Service. West Conshohocken, PA; ASTM International, 2018. doi : 10.1520/A0874_A0874M-98R18E01
  9. Aluminum ADI

Bibliography