The HAZMAT Class 2 in United States law includes all gases which are compressed and stored for transportation. Class 2 has three divisions: Flammable (also called combustible), Non-Flammable/Non-Poisonous, and Poisonous. This classification is based on the United Nations' Recommendations on the Transport of Dangerous Goods - Model Regulations. In Canada, the Transportation of Dangerous Goods Regulations, or TDGR, are also based on the UN Model Regulations and contain the same three divisions.
A gas is a substance which
Gases are assigned to one of three divisions
Aerosols also fall into Class 2 divisions where an aerosol is defined as an article consisting of any non-refillable receptacle containing a gas compressed, liquefied or dissolved under pressure, the sole purpose of which is to expel a nonpoisonous (other than a Division 6.1 Packing Group III material) liquid, paste, or powder and fitted with a self-closing release device allowing the contents to be ejected by the gas.
Division 2.1: Flammable, Non-Toxic Gas
Flammable gas means any material that:
The following applies to aerosols:
Division 2.2: Non-Flammable, Non-Toxic Gas
This division includes compressed gas, liquefied gas, pressurized cryogenic gas, compressed gas in solution, asphyxiant gas and oxidizing gas. A non-flammable, nonpoisonous compressed gas (Division 2.2) means any material (or mixture) which:
A non-flammable gas means any material that:
The following applies to aerosols:
Division 2.3: Toxic Gas
Gas poisonous by inhalation means a material which is a gas at 20 °C or less and a pressure of 101.3 kPa (a material which has a boiling point of 20 °C or less at 101.3kPa (14.7 psi)) and which:
Load and Segregation Chart | ||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Weight | 1.1 | 1.2 | 1.3 | 1.4 | 1.5 | 1.6 | 2.1 | 2.2 | 2.2 | 2.3 | 3 | 4.1 | 4.2 | 4.3 | 5.1 | 5.2 | 6.1 | 7 | 8 | |||
A | B | A | ||||||||||||||||||||
2.1 | 1,001 lb (454 kg) | O | O | O | O | |||||||||||||||||
2.2 | 1,001 lb (454 kg) | B | O | |||||||||||||||||||
2.2 | 1,001 lb (454 kg) | B | O | |||||||||||||||||||
2.3A | Any Quantity | O | ||||||||||||||||||||
2.3B | Any Quantity | O | O | O | O | O | O | O | O | |||||||||||||
Key | ||||||||||||||||||||||
The absence of any hazard class or division or a blank space in the table indicates that no restrictions apply.
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Pressure is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure is the pressure relative to the ambient pressure.
Standard temperature and pressure (STP) are standard sets of conditions for experimental measurements to be established to allow comparisons to be made between different sets of data. The most used standards are those of the International Union of Pure and Applied Chemistry (IUPAC) and the National Institute of Standards and Technology (NIST), although these are not universally accepted standards. Other organizations have established a variety of alternative definitions for their standard reference conditions.
UN number is a four-digit number that identifies hazardous materials, and articles in the framework of international trade and transport. Some hazardous substances have their own UN numbers, while sometimes groups of chemicals or products with similar properties receive a common UN number. A chemical in its solid state may receive a different UN number than the liquid phase if its hazardous properties differ significantly; substances with different levels of purity may also receive different UN numbers.
Liquefied petroleum gas is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane and butane.
A diving cylinder or diving gas cylinder is a gas cylinder used to store and transport high pressure gas used in diving operations. This may be breathing gas used with a scuba set, in which case the cylinder may also be referred to as a scuba cylinder, scuba tank or diving tank. When used for an emergency gas supply for surface supplied diving or scuba, it may be referred to as a bailout cylinder or bailout bottle. It may also be used for surface-supplied diving or as decompression gas. A diving cylinder may also be used to supply inflation gas for a dry suit or buoyancy compensator. Cylinders provide gas to the diver through the demand valve of a diving regulator or the breathing loop of a diving rebreather.
Spray painting is a painting technique in which a device sprays coating material through the air onto a surface. The most common types employ compressed gas—usually air—to atomize and direct the paint particles.
Aerosol spray is a type of dispensing system which creates an aerosol mist of liquid particles. It comprises a can or bottle that contains a payload, and a propellant under pressure. When the container's valve is opened, the payload is forced out of a small opening and emerges as an aerosol or mist.
A gas cylinder is a pressure vessel for storage and containment of gases at above atmospheric pressure. High-pressure gas cylinders are also called bottles. Inside the cylinder the stored contents may be in a state of compressed gas, vapor over liquid, supercritical fluid, or dissolved in a substrate material, depending on the physical characteristics of the contents. A typical gas cylinder design is elongated, standing upright on a flattened bottom end, with the valve and fitting at the top for connecting to the receiving apparatus.
Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials. An example for dangerous goods is hazardous waste which is waste that has substantial or potential threats to public health or the environment.
ADR, formally the Agreement of 30 September 1957 concerning the International Carriage of Dangerous Goods by Road is a 1957 United Nations treaty that governs transnational transport of hazardous materials. "ADR" is derived from the French name for the treaty: Accord relatif au transport international des marchandises Dangereuses par Route). Until 31 December 2020, the treaty was fully named European Agreement concerning the International Carriage of Dangerous Goods by Road. However, as the word "European" might have given the impression that the treaty was only open for accession to European states, an amendment was decided in the end of 2019.
A standard cubic foot (scf) is a unit used both in the natural gas industry to represent an amount of natural gas and in other industries where other gases are used. It is the unit commonly used when following the customary system, a collection of standards set by the National Institute of Standards and Technology. Another unit used for the same purpose is the standard cubic metre (Sm3), customary when using SI units.
Medical gas supply systems in hospitals and other healthcare facilities are utilized to supply specialized gases and gas mixtures to various parts of the facility. Products handled by such systems typically include:
ORM-D was a marking for mail or shipping in the United States. Packages bearing this mark contained hazardous material in a limited quantity that present a limited hazard during transportation, due to its form, quantity, and packaging. ORM-D was phased out by the US Department of Transportation on Jan. 1, 2021.
A Salvage Drum is an outer container used for shipping a leaking, damaged or non-compliant drum containing hazardous materials.
An oxidizer is a chemical that readily yields oxygen in reactions, thereby causing or enhancing combustion.
Flammable solids are any materials in the solid phase of matter that can readily undergo combustion in the presence of a source of ignition under standard circumstances, i.e. without:
Poisonous material is a material, other than a gas, known to be so toxic to humans that it presents a health hazard during transportation.
The pound per square inch or, more accurately, pound-force per square inch is a unit of pressure or of stress based on avoirdupois units. It is the pressure resulting from a force of one pound-force applied to an area of one square inch. In SI units, 1 psi is approximately equal to 6895 Pa.
The Hazardous Materials Transportation Act (HMTA), enacted in 1975, is the principal federal law in the United States regulating the transportation of hazardous materials. Its purpose is to "protect against the risks to life, property, and the environment that are inherent in the transportation of hazardous material in intrastate, interstate, and foreign commerce" under the authority of the United States Secretary of Transportation.
Many laboratories contain significant risks, and the prevention of laboratory accidents requires great care and constant vigilance. Examples of risk factors include high voltages, high and low pressures and temperatures, corrosive and toxic chemicals and chemical vapours, radiation, fire, explosions, and biohazards including infective organisms and their toxins.