HAZMAT Class 5 Oxidizing agents and organic peroxides

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An oxidizer is a chemical that readily yields oxygen in reactions, thereby causing or enhancing combustion.

Contents

Divisions

Division 5.1: Oxidizers

HAZMAT 5.1 placard on a pail of UN 2468,Trichloroisocyanuric acid for use in swimming pools. Oxidizer 5.1 hazmat logo.jpg
HAZMAT 5.1 placard on a pail of UN 2468,Trichloroisocyanuric acid for use in swimming pools.

An oxidizer is a material that may, generally by yielding oxygen, cause or enhance the combustion of other materials.

  1. A solid material is classed as a Division 5.1 material if, when tested in accordance with the UN Manual of Tests and Criteria, its mean burning time is less than or equal to the burning time of a 3:7 potassium bromate/cellulose mixture.
  2. A liquid material is classed as a Division 5.1 material if, when tested in accordance with the UN Manual of Tests and Criteria, it spontaneously ignites or its mean time for a pressure rise from 690 kPa to 2070 kPa gauge is less than the time of a 1:1 nitric acid (65 percent)/cellulose mixture.

Division 5.2: Organic Peroxides

An organic peroxide is any organic compound containing oxygen (O) in the bivalent -O-O- structure and which may be considered a derivative of hydrogen peroxide, where one or more of the hydrogen atoms have been replaced by organic radicals, unless any of the following paragraphs applies:

  1. The material meets the definition of an explosive as prescribed in subpart C of this part, in which case it must be classed as an explosive (applies to acetone peroxide, for example)
  2. The material is forbidden from being offered for transportation according to 49CFR 172.101 of this subchapter or 49CFR 173.21;
  3. The Associate Administrator for Hazardous Materials Safety has determined that the material does not present a hazard which is associated with a Division 5.2 material; or
  4. The material meets one of the following conditions:
  • For materials containing no more than 1.0 percent hydrogen peroxide, the available oxygen, as calculated using the equation in paragraph (a)(4)(ii) of this section, is not more than 1.0 percent, or
  • For materials containing more than 1.0 percent but not more than 7.0 percent hydrogen peroxide, the available oxygen content (Oa) is not more than 0.5 percent, when determined using the equation:
Oa = 16x
where for a material containing k species of organic peroxides:
= number of -O-O- groups per molecule of the species
= concentration (mass percent) of the species
= molecular mass of the species

Placards

UN transport pictogram - 5.1.svg Hazardous Materials
Class 5.1: Oxidizing Agent
UN transport pictogram - 5.2 (white).svg Hazardous Materials
Class 5.2: Organic Peroxide Oxidizing Agent

Prior to 2007, the placard for 'Organic Peroxide' (5.2) was entirely yellow, like placard 5.1.

Compatibility Table

Load and Segregation Chart
 Weight1.11.21.31.41.51.62.12.22.22.334.14.24.35.15.26.178
ABA
5.11,001 lb (454 kg)ADark Red x.svgDark Red x.svgDark Red x.svg Dark Red x.svg    Dark Red x.svgOO     Dark Red x.svg O
5.21,001 lb (454 kg)Dark Red x.svgDark Red x.svgDark Red x.svg Dark Red x.svg    Dark Red x.svgO      Dark Red x.svg O
Key
The absence of any hazard class or division or a blank space in the table indicates that no restrictions apply.
  • X: These materials may not be loaded, transported, or stored together in the same transport vehicle or storage facility during the course of transportation.
  • O: Indicates that these materials may not be loaded, transported or stored together in the same transport vehicle or storage facility during the course of transportation, unless separated in a manner that, in the event of leakage from packages under conditions normally incident to transportation, commingling of hazardous materials would not occur.
  • A: This note means that, notwithstanding the requirements of the letter 'X', ammonium nitrate fertilizer may be loaded or stored with Division 1.1 or Division 1.5 materials.


Source: United States Code of Federal Regulations, Title 49 CFR §177.848 - Segregation of hazardous materials. [1]

Packing Groups

Class 5 Packing Groups
GroupDivisionPhaseDetails
Group I5.1SolidAny material which, in either concentration tested, exhibits a mean burning time less than the mean burning time of a 3:2 potassium bromate/cellulose mixture.
Group II5.1SolidAny material which, in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I are not met.
Group III5.1SolidAny material which, in either concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met.
Group I5.1Liquid
  1. Any material which spontaneously ignites when mixed with cellulose in a 1:1 ratio; or
  2. Any material which exhibits a mean pressure rise time less than the pressure rise time of a 1:1 perchloric acid (50 percent)/cellulose mixture.
Group II5.1LiquidAny material which exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 aqueous sodium chlorate solution(40 percent)/cellulose mixture and the criteria for Group I are not met.
Group III5.1LiquidAny material which exhibits a mean pressure rise time less than or equal to the pressure rise time of a 1:1 nitric acid (65 percent)/cellulose mixture and the criteria for Packing Group I and II are not met.
Group II5.2AllAll Division 5.2 materials do not have a packing group in Column 5 of the 49 CFR 172.101 Table.

Related Research Articles

Combustion Chemical reaction

Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion, the heat from a flame may provide enough energy to make the reaction self-sustaining.

Explosive Substance that can explode

An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.

Hydrogen peroxide Chemical compound

Hydrogen peroxide is a chemical compound with the formula H2O2. In its pure form, it is a very pale blue liquid, slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution in water for consumer use, and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or "high-test peroxide", decomposes explosively when heated and has been used as a propellant in rocketry.

Oxygen Chemical element, symbol O and atomic number 8

Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula O
2
. Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.

Hybrid-propellant rocket Rocket engine that uses both liquid / gaseous and solid fuel

A hybrid-propellant rocket is a rocket with a rocket motor that uses rocket propellants in two different phases: one solid and the other either gas or liquid. The hybrid rocket concept can be traced back to at least the 1930s.

Redox Chemical reaction in which oxidation states of atoms are changed

Redox is a type of chemical reaction in which the oxidation states of substrate change.

Oxidizing agent Chemical compound used to oxidize another substance in a chemical reaction

An oxidizing agent is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent. In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens.

Chemiluminescence Emission of light as a result of a chemical reaction

Chemiluminescence is the emission of light (luminescence) as the result of a chemical reaction. There may also be limited emission of heat. Given reactants A and B, with an excited intermediate ,

Sterilization (microbiology) Process that eliminates or kills all biological agents on an object or in a volume

Sterilization refers to any process that removes, kills, or deactivates all forms of life and other biological agents such as prions present in or on a specific surface, object, or fluid. Sterilization can be achieved through various means, including heat, chemicals, irradiation, high pressure, and filtration. Sterilization is distinct from disinfection, sanitization, and pasteurization, in that those methods reduce rather than eliminate all forms of life and biological agents present. After sterilization, an object is referred to as being sterile or aseptic.

Biochemical oxygen demand Oxygen needed to remove organics from water

Biochemical oxygen demand (BOD) is the amount of dissolved oxygen (DO) needed by aerobic biological organisms to break down organic material present in a given water sample at certain temperature over a specific time period. The BOD value is most commonly expressed in milligrams of oxygen consumed per litre of sample during 5 days of incubation at 20 °C and is often used as a surrogate of the degree of organic pollution of water.

Organic peroxides Type of organic compounds

Organic peroxides are organic compounds containing the peroxide functional group (ROOR′). If the R′ is hydrogen, the compounds are called hydroperoxides, which are discussed in that article. Peresters are the peroxy analog of esters and have general structure RC(O)OOR. The O−O bond of peroxides easily breaks, producing free radicals of the form RO. Thus, organic peroxides are useful as initiators for some types of polymerisation, such as the epoxy resins used in glass-reinforced plastics. MEKP and benzoyl peroxide are commonly used for this purpose. However, the same property also means that organic peroxides can either intentionally or unintentionally initiate explosive polymerisation in materials with unsaturated chemical bonds, and this process has been used in explosives. Organic peroxides, like their inorganic counterparts, are powerful bleaching agents.

Piranha solution Oxidizing acid mixture containing sulfuric acid and hydrogen peroxide

Piranha solution, also known as piranha etch, is a mixture of sulfuric acid and hydrogen peroxide, used to clean organic residues off substrates. Because the mixture is a strong oxidizing agent, it will decompose most organic matter, and it will also hydroxylate most surfaces, making them highly hydrophilic (water-compatible). This means the solution can also easily dissolve fabric and skin, potentially causing severe damage and chemical burns in case of inadvertent contact.

Dakin oxidation

The Dakin oxidation is an organic redox reaction in which an ortho- or para-hydroxylated phenyl aldehyde or ketone reacts with hydrogen peroxide in base to form a benzenediol and a carboxylate. Overall, the carbonyl group is oxidized, and the hydrogen peroxide is reduced.

Zinc peroxide Chemical compound

Zinc peroxide (ZnO2) appears as a bright yellow powder at room temperature. It was historically used as a surgical antiseptic. More recently zinc peroxide has also been used as an oxidant in explosives and pyrotechnic mixtures. Its properties have been described as a transition between ionic and covalent peroxides. Zinc peroxide can be synthesized through the reaction of zinc chloride and hydrogen peroxide.

A flammable liquid is a liquid with flash point of not more than 60.5 °C (141 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging.

The HAZMAT Class 2 in United States law includes all gases which are compressed and stored for transportation. Class 2 has three divisions: Flammable, Non-Flammable/Non-Poisonous, and Poisonous. This classification is based on the United Nations' Recommendations on the Transport of Dangerous Goods - Model Regulations. In Canada, the Transportation of Dangerous Goods Regulations, or TDGR, are also based on the UN Model Regulations and contain the same three divisions.

Bleaching of wood pulp is the chemical processing of wood pulp to lighten its color and whiten the pulp. The primary product of wood pulp is paper, for which whiteness is an important characteristic. These processes and chemistry are also applicable to the bleaching of non-wood pulps, such as those made from bamboo or kenaf.

Photoinitiator

A photoinitiator is a molecule that creates reactive species when exposed to radiation. Synthetic photoinitiators are key components in photopolymers.

Oxygen compounds

The oxidation state of oxygen is −2 in almost all known compounds of oxygen. The oxidation state −1 is found in a few compounds such as peroxides. Compounds containing oxygen in other oxidation states are very uncommon: −12 (superoxides), −13 (ozonides), 0, +12 (dioxygenyl), +1, and +2.

Rocket propellant Chemical or mixture used as fuel for a rocket engine

Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines.

References

  1. Pipeline and Hazardous Materials Safety Administration (PHMSA) (October 1, 2011). "49 CFR 177.848 - Segregation of hazardous materials" (PDF). Government Publishing Office. p. 853. Archived from the original (PDF) on 16 July 2019. Retrieved 16 July 2019.