Tryptophan dimethylallyltransferase

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tryptophan dimethylallyltransferase
Identifiers
EC no. 2.5.1.34
CAS no. 55127-01-0
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MetaCyc metabolic pathway
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In enzymology, a tryptophan dimethylallyltransferase (EC 2.5.1.34) is an enzyme that catalyzes the chemical reaction

dimethylallyl diphosphate + L-tryptophan diphosphate + 4-(3-methylbut-2-enyl)-L-tryptophan

Thus, the two substrates of this enzyme are dimethylallyl diphosphate and L-tryptophan, whereas its two products are diphosphate and 4-(3-methylbut-2-enyl)-L-tryptophan.

This enzyme belongs to the family of transferases, specifically those transferring aryl or alkyl groups other than methyl groups. The systematic name of this enzyme class is dimethylallyl-diphosphate:L-tryptophan dimethylallyltransferase. Other names in common use include dimethylallylpyrophosphate:L-tryptophan dimethylallyltransferase, dimethylallyltryptophan synthetase, dimethylallylpyrophosphate:tryptophan dimethylallyl transferase, DMAT synthetase, and 4-(gamma,gamma-dimethylallyl)tryptophan synthase.

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4-Hydroxy-3-methylbut-2-enyl diphosphate reductase (EC 1.17.1.2, isopentenyl-diphosphate:NADP+ oxidoreductase, LytB, (E)-4-hydroxy-3-methylbut-2-en-1-yl diphosphate reductase, HMBPP reductase, IspH, LytB/IspH) is an enzyme in the non-mevalonate pathway. It acts upon (E)-4-Hydroxy-3-methyl-but-2-enyl pyrophosphate (or "HMB-PP").

4-dimethylallyltryptophan N-methyltransferase is an enzyme with systematic name S-adenosyl-L-methionine:4-(3-methylbut-2-enyl)-L-tryptophan N-methyltransferase. This enzyme catalyses the following chemical reaction

Trihydroxypterocarpan dimethylallyltransferase is an enzyme with systematic name dimethylallyl-diphosphate:(6aS,11aS)-3,6a,9-trihydroxypterocarpan dimethylallyltransferase. This enzyme catalyses the following chemical reaction

Leachianone-G 2''-dimethylallyltransferase is an enzyme with systematic name dimethylallyl-diphosphate:leachianone-G 2''-dimethylallyltransferase. This enzyme catalyses the following chemical reaction:

TRNA dimethylallyltransferase is an enzyme with systematic name dimethylallyl-diphosphate: tRNA dimethylallyltransferase. This enzyme catalyses the following chemical reaction

7-dimethylallyltryptophan synthase is an enzyme with systematic name dimethylallyl-diphosphate:L-tryptophan 7-dimethylallyltransferase. This enzyme catalyses the following chemical reaction

Fumigaclavine A dimethylallyltransferase is an enzyme with systematic name dimethylallyl-diphosphate:fumigaclavine A dimethylallyltransferase. This enzyme catalyses the following chemical reaction

References