Zirconium lactate

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Zirconium lactate
Zirconium lactate.svg
Names
Other names
Zirconium(IV) lactate
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
UNII
  • InChI=1S/4C3H5O3.Zr/c4*1-2(4)3(5)6;/h4*2H,1H3,(H,5,6);/q4*-1;+4 Yes check.svgY
    Key: JVIFSUQNYWNEHY-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/4C3H5O3.Zr/c4*1-2(4)3(5)6;/h4*2H,1H3,(H,5,6);/q4*-1;+4
    Key: JVIFSUQNYWNEHY-UHFFFAOYAJ
  • [Zr+4].O=C(O)C([O-])C.[O-]C(C(=O)O)C.[O-]C(C(=O)O)C.[O-]C(C(=O)O)C
Properties
C12H20O12Zr
Molar mass 447.504 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Zirconium lactate is the zirconium salt of lactic acid. It is used in some deodorants. It is a colourless solid. Zirconium carboxylates adopt highly complex structures and are heterogeneous compositions with the approximate formula Zr(OH)4-n(O2CCHOHCH3)n(H2O)x where 1 < n < 3. [1]

It is also used in the petroleum industry as a cross-linking agent to prepare gels for fracturing fluids, fluids which are pumped into an oil-bearing rock formation to cause cracks in the rock and so to allow the oil to be extracted. [2] It may be prepared by treating zirconium oxide with lactic acid. [2]

Safety

Its LD50  >10 g/kg). [3] It is suspected of causing zirconium granulomas (a form of skin irritation) in a small number of users. [4]

Related Research Articles

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<span class="mw-page-title-main">Lactic acid</span> Group of stereoisomers

Lactic acid is an organic acid. It has a molecular formula CH3CH(OH)COOH. It is white in the solid state and it is miscible with water. When in the dissolved state, it forms a colorless solution. Production includes both artificial synthesis as well as natural sources. Lactic acid is an alpha-hydroxy acid (AHA) due to the presence of a hydroxyl group adjacent to the carboxyl group. It is used as a synthetic intermediate in many organic synthesis industries and in various biochemical industries. The conjugate base of lactic acid is called lactate (or the lactate anion). The name of the derived acyl group is lactoyl.

<span class="mw-page-title-main">Lactic acid fermentation</span> Metabolic process

Lactic acid fermentation is a metabolic process by which glucose or other six-carbon sugars are converted into cellular energy and the metabolite lactate, which is lactic acid in solution. It is an anaerobic fermentation reaction that occurs in some bacteria and animal cells, such as muscle cells.

<span class="mw-page-title-main">Lactic acidosis</span> Metabolic medical condition

Lactic acidosis is a medical condition characterized by a build-up of lactate in the body, with formation of an excessively low pH in the bloodstream. It is a form of metabolic acidosis, in which excessive acid accumulates due to a problem with the body's oxidative metabolism.

<span class="mw-page-title-main">Hydrofluoric acid</span> Solution of hydrogen fluoride in water

Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colourless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers.

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Acidosis is a process causing increased acidity in the blood and other body tissues. If not further qualified, it usually refers to acidity of the blood plasma.

<span class="mw-page-title-main">Hypovolemic shock</span> Medical condition

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<span class="mw-page-title-main">Cori cycle</span> Lactate degrading metabolic pathway

The Cori cycle, named after its discoverers, Carl Ferdinand Cori and Gerty Cori, is a metabolic pathway in which lactate, produced by anaerobic glycolysis in muscles, is transported to the liver and converted to glucose, which then returns to the muscles and is cyclically metabolized back to lactate.

<span class="mw-page-title-main">Ringer's lactate solution</span>

Ringer's lactate solution (RL), also known as sodium lactate solution,Lactated Ringer’s, and Hartmann's solution, is a mixture of sodium chloride, sodium lactate, potassium chloride, and calcium chloride in water. It is used for replacing fluids and electrolytes in those who have low blood volume or low blood pressure. It may also be used to treat metabolic acidosis and to wash the eye following a chemical burn. It is given by intravenous infusion or applied to the affected area.

<span class="mw-page-title-main">Polylactic acid</span> Biodegradable polymer

Polylactic acid, also known as poly(lactic acid) or polylactide (PLA), is a thermoplastic polyester with backbone formula (C
3
H
4
O
2
)
n
or [–C(CH
3
)HC(=O)O–]
n
, formally obtained by condensation of lactic acid C(CH
3
)(OH)HCOOH
with loss of water. It can also be prepared by ring-opening polymerization of lactide [–C(CH
3
)HC(=O)O–]
2
, the cyclic dimer of the basic repeating unit.

<span class="mw-page-title-main">Calcium lactate</span> Chemical compound

Calcium lactate is a white crystalline salt with formula C
6
H
10
CaO
6
, consisting of two lactate anions H
3
C
(CHOH)CO
2
for each calcium cation Ca2+
. It forms several hydrates, the most common being the pentahydrate C
6
H
10
CaO
6
·5H
2
O
.

<span class="mw-page-title-main">Lactate dehydrogenase</span> Class of enzymes

Lactate dehydrogenase (LDH or LD) is an enzyme found in nearly all living cells. LDH catalyzes the conversion of lactate to pyruvate and back, as it converts NAD+ to NADH and back. A dehydrogenase is an enzyme that transfers a hydride from one molecule to another.

<span class="mw-page-title-main">High anion gap metabolic acidosis</span> Medical condition

High anion gap metabolic acidosis is a form of metabolic acidosis characterized by a high anion gap. Metabolic acidosis occurs when the body produces too much acid, or when the kidneys are not removing enough acid from the body. Several types of metabolic acidosis occur, grouped by their influence on the anion gap.

<span class="mw-page-title-main">Fracking</span> Fracturing bedrock by pressurized liquid

Fracking is a well stimulation technique involving the fracturing of bedrock formations by a pressurized liquid. The process involves the high-pressure injection of "fracking fluid" into a wellbore to create cracks in the deep-rock formations through which natural gas, petroleum, and brine will flow more freely. When the hydraulic pressure is removed from the well, small grains of hydraulic fracturing proppants hold the fractures open.

<span class="mw-page-title-main">Lithium lactate</span> Chemical compound

Lithium lactate is a chemical compound, a salt of lithium and lactic acid with the formula CH3CH(OH)COOLi, an amorphous solid, very soluble in water.

<span class="mw-page-title-main">Aluminium lactate</span> Chemical compound

Aluminium lactate is a chemical compound, a salt of aluminium and lactic acid with the formula Al(C3H5O3)3.

References

  1. Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. doi : 10.1002/14356007.a28_543
  2. 1 2 Dawson, Jeffrey C.; Le Hoang, Van (31 October 1996), "Gelation Additive for Hydraulic Fracturing Fluids", International Patent Application, WO9633966
  3. Brown, J. R.; Mastromatteo, E.; Horwood, J. (1963), "Zirconium lactate and barium zirconate. Acute toxicity and inhalation effects in experimental animals", Am. Ind. Hyg. Assoc. J., 24 (2): 131–366, doi:10.1080/00028896309342940, PMID   14015998
  4. James, William D.; Berger, Timothy G.; et al. (2006), Andrews' Diseases of the Skin: Clinical Dermatology, Saunders Elsevier, p. 46, ISBN   0-7216-2921-0